Sigman, Matt
Publication with MATCHING institution:
- Yuan Q, Prater MB, Sigman M (2019) Enantioselective Synthesis of γ-Functionalized Cyclopentenones and δ-Functionalized
Cycloheptenones Utilizing a Redox-Relay Heck Strategy. Advanced Synthesis and Catalysis. [IF=1.04, Cited=2, 33447174].
- Avila CM, Patel JS, Reddi Y, ..., Toste FD (2017) Enantioselective Heck-Matsuda Arylations through Chiral Anion Phase-
Transfer of Aryl Diazonium Salts. Angewandte Chemie - International Edition. [IF=2.456, Cited=16, 28418118].
- Chen ZM, Nervig CS, DeLuca RJ, Sigman M (2017) Palladium-Catalyzed Enantioselective Redox-Relay Heck Alkynylation of
Alkenols To Access Propargylic Stereocenters. Angewandte Chemie - International Edition. [IF=2.456, Cited=20, 28467031].
- Orlandi M, Toste FD, Sigman M (2017) Multidimensional Correlations in Asymmetric Catalysis through Parameterization of
Uncatalyzed Transition States. Angewandte Chemie - International Edition. [IF=2.456, Cited=11, 28902441].
- Biswas S, Kubota K, Orlandi M, ..., Toste FD (2017) Enantioselective Synthesis of N,S-Acetals by an Oxidative Pummerer-
Type Transformation using Phase-Transfer Catalysis. Angewandte Chemie - International Edition. [IF=2.456, Cited=13, 29171138].
- Tsai CC, Sandford C, Wu T, ..., Toste FD (2020) Enantioselective Intramolecular Allylic Substitution via Synergistic
Palladium/Chiral Phosphoric Acid Catalysis: Insight into Stereoinduction through Statistical Modeling. Angewandte Chemie
- International Edition. [IF=2.456, Cited=5, 32453890].
- Yan Y, Vogt DB, Vaid TP, ..., Sanford MS (2021) Development of High Energy Density Diaminocyclopropenium-Phenothiazine
Hybrid Catholytes for Non-Aqueous Redox Flow Batteries. Angewandte Chemie - International Edition. [IF=2.456, Cited=8, 34672070].
- Rein J, Meinhardt JM, Hofstra Wahlman JL, ..., Lin S (2023) A Physical Organic Approach towards Statistical Modeling of
Tetrazole and Azide Decomposition. Angewandte Chemie - International Edition. [IF=2.456, Cited=0, 36823344].
- Race NJ, Yuan Q, Sigman M (2018) Enantioselective C2-Alkylation of Indoles through a Redox-Relay Heck Reaction of
2-Indole Triflates. Chemistry - A European Journal. [IF=0.899, Cited=6, 30402891].
- Yuan Q, Sigman M (2019) Palladium-Catalyzed Enantioselective Alkenylation of Enelactams Using a Relay Heck Strategy.
Chemistry - A European Journal. [IF=0.899, Cited=4, 31216370].
- Vaid TP, Cook ME, Scott JD, ..., Sanford MS (2022) Theoretical and Experimental Investigation of Functionalized
Cyanopyridines Yield an Anolyte with an Extremely Low Reduction Potential for Nonaqueous Redox Flow Batteries. Chemistry
- A European Journal. [IF=0.899, Cited=1, 36164261].
- Prater MB, Sigman M (2019) Enantioselective Synthesis of Alkyl Allyl Ethers via Palladium-Catalyzed Redox-Relay Heck
Alkenylation of O-Alkyl Enol Ethers. Israel Journal of Chemistry. [IF=0.673, Cited=4, 33446940].
- Liles JP, Rouget-Virbel C, Wahlman JLH, ..., Sigman M (2023) Data Science Enables the Development of a New Class of
Chiral Phosphoric Acid Catalysts. Chem. [IF=2.863, Cited=6, 37519827].
- Hilton MJ, Cheng B, Buckley BR, ..., Sigman M (2015) Relative reactivity of alkenyl alcohols in the palladium-catalyzed
redox-relay Heck reaction. Tetrahedron. [IF=0.579, Cited=13, 26392640].
- Crawford JM, Kingston C, Toste FD, Sigman M (2021) Data Science Meets Physical Organic Chemistry. Accounts of Chemical
Research. [IF=3.533, Cited=15, 34351757].
- Walser-Kuntz R, Yan Y, Sigman M, Sanford MS (2023) A Physical Organic Chemistry Approach to Developing Cyclopropenium-
Based Energy Storage Materials for Redox Flow Batteries. Accounts of Chemical Research. [IF=3.533, Cited=3, 37094181].
- Sigman M, Harper KC, Bess EN, Milo A (2016) The Development of Multidimensional Analysis Tools for Asymmetric Catalysis
and Beyond. Accounts of Chemical Research. [IF=3.533, Cited=102, 27220055].
- Toste FD, Sigman M, Sigman MS, ..., Miller SJ (2017) Pursuit of Noncovalent Interactions for Strategic Site-Selective
Catalysis. Accounts of Chemical Research. [IF=3.533, Cited=66, 28945415].
- Robinson SG, Sigman M (2020) Integrating Electrochemical and Statistical Analysis Tools for Molecular Design and
Mechanistic Understanding. Accounts of Chemical Research. [IF=3.533, Cited=3, 31920070].
- Xu L, Zhang X, McCammant MS, ..., Wiest O (2016) Mechanism and Selectivity in the Pd-Catalyzed Difunctionalization of
Isoprene. Journal of Organic Chemistry. [IF=0.885, Cited=2, 27486829].
- Robinson SG, Mack JBC, Alektiar SN, ..., Sigman MS (2020) Electrochemical Ruthenium-Catalyzed C-H Hydroxylation of Amine
Derivatives in Aqueous Acid. Organic Letters. [IF=1.091, Cited=3, 32419465].
- Kraus SL, Ross SP, Sigman M (2021) Rate Profiling the Impact of Remote Functional Groups on the Redox-Relay Heck
Reaction. Organic Letters. [IF=1.091, Cited=0, 33710906].
- McCammant MS, Shigeta T, Sigman M (2016) Palladium-Catalyzed 1,3-Difunctionalization Using Terminal Alkenes with Alkenyl
Nonaflates and Aryl Boronic Acids. Organic Letters. [IF=1.091, Cited=8, 27019228].
- Werth J, Sigman M (2021) Linear Regression Model Development for Analysis of Asymmetric Copper-Bisoxazoline Catalysis.
ACS Catalysis. [IF=2.134, Cited=4, 34671510].
- Samha MH, Wahlman JLH, Read JA, ..., Sigman MS (2022) Exploring Structure-Function Relationships of Aryl Pyrrolidine-
Based Hydrogen-Bond Donors in Asymmetric Catalysis Using Data-Driven Techniques. ACS Catalysis. [IF=2.134, Cited=1, 36816226].
- Souza LW, Miller BR, Cammarota RC, ..., Shaw JT (2023) Deconvoluting Nonlinear Catalyst-Substrate Effects in the
Intramolecular Dirhodium-Catalyzed C-H Insertion of Donor/Donor Carbenes Using Data Science Tools. ACS Catalysis.
[IF=2.134, Cited=0, 38205021].
- Christian AH, Niemeyer ZL, Sigman M, Toste FD (2017) Uncovering Subtle Ligand Effects of Phosphines Using Gold(I)
Catalysis. ACS Catalysis. [IF=2.134, Cited=20, 29686935].
- Li J, Grosslight S, Miller S, ..., Toste FD (2019) Site-selective acylation of natural products with BINOL-derived
phosphoric acids. ACS Catalysis. [IF=2.134, Cited=6, 31827975].
- Williams WL, Zeng L, Gensch T, ..., Anslyn EV (2021) The Evolution of Data-Driven Modeling in Organic Chemistry. ACS
Central Science. [IF=2.363, Cited=30, 34729406].
- Raghavan P, Haas BC, Ruos ME, ..., Coley CW (2023) Dataset Design for Building Models of Chemical Reactivity. ACS
Central Science. [IF=2.363, Cited=4, 38161380].
- Hendriks KH, Robinson SG, Braten MN, ..., Sanford MS (2018) High-Performance Oligomeric Catholytes for Effective
Macromolecular Separation in Nonaqueous Redox Flow Batteries. ACS Central Science. [IF=2.363, Cited=22, 29532018].
- Vaden RM, Guillen KP, Salvant JM, ..., Welm BE (2019) A Cancer-Selective Zinc Ionophore Inspired by the Natural Product
Naamidine A. ACS Chemical Biology. [IF=0.963, Cited=5, 30571086].
- Sigman M, Jensen DR (2006) Ligand-modulated palladium-catalyzed aerobic alcohol oxidations. Accounts of Chemical
Research. [IF=3.533, Cited=141, 16548511].
- Sigman M, Werner EW (2011) Imparting catalyst control upon classical palladium-catalyzed alkenyl C-H bond
functionalization reactions. Accounts of Chemical Research. [IF=3.533, Cited=53, 22111756].
- Jana R, Pathak TP, Sigman M (2011) Advances in transition metal (Pd, Ni, Fe)-catalyzed cross-coupling reactions using
alkyl-organometallics as reaction partners. Chemical Reviews. [IF=11.712, Cited=481, 21319862].
- Dible BR, Sigman M (2005) Oxygen-induced ligand dehydrogenation of a planar bis-mu-chloronickel(I) dimer featuring an
NHC ligand. Inorganic Chemistry. [IF=0.986, Cited=40, 15907100].
- Dible BR, Sigman M (2006) Steric effects in the aerobic oxidation of pi-allylnickel(II) complexes with N-heterocyclic
carbenes. Inorganic Chemistry. [IF=0.986, Cited=11, 16999444].
- Cornell CN, Sigman M (2007) Recent progress in Wacker oxidations: moving toward molecular oxygen as the sole oxidant.
Inorganic Chemistry. [IF=0.986, Cited=50, 17348721].
- Jensen DR, Pugsley JS, Sigman M (2001) Palladium-catalyzed enantioselective oxidations of alcohols using molecular
oxygen. Journal of the American Chemical Society. [IF=2.573, Cited=64, 11472200].
- Mueller JA, Jensen DR, Sigman M (2002) Dual role of (-)-sparteine in the palladium-catalyzed aerobic oxidative kinetic
resolution of secondary alcohols. Journal of the American Chemical Society. [IF=2.573, Cited=22, 12105896].
- Dible BR, Sigman M (2003) Unusual reactivity of molecular oxygen with pi-allylnickel(N-heterocyclic carbene) chloride
complexes. Journal of the American Chemical Society. [IF=2.573, Cited=15, 12537477].
- Mueller JA, Sigman M (2003) Mechanistic investigations of the palladium-catalyzed aerobic oxidative kinetic resolution
of secondary alcohols using (-)-sparteine. Journal of the American Chemical Society. [IF=2.573, Cited=27, 12783555].
- Cornell CN, Sigman M (2005) Discovery of and mechanistic insight into a ligand-modulated palladium-catalyzed Wacker
oxidation of styrenes using TBHP. Journal of the American Chemical Society. [IF=2.573, Cited=27, 15740083].
- Mueller JA, Goller CP, Sigman M (2004) Elucidating the significance of beta-hydride elimination and the dynamic role of
acid/base chemistry in a palladium-catalyzed aerobic oxidation of alcohols. Journal of the American Chemical Society.
[IF=2.573, Cited=58, 15291576].
- Schultz MJ, Adler RS, Zierkiewicz W, ..., Sigman M (2005) Using mechanistic and computational studies to explain ligand
effects in the palladium-catalyzed aerobic oxidation of alcohols. Journal of the American Chemical Society. [IF=2.573,
Cited=31, 15941285].
- Mueller JA, Cowell A, Chandler BD, Sigman M (2005) Origin of enantioselection in chiral alcohol oxidation catalyzed by
Pd[(-)-sparteine]Cl2. Journal of the American Chemical Society. [IF=2.573, Cited=19, 16231935].
- Schultz MJ, Sigman M (2006) Palladium(II)-catalyzed aerobic dialkoxylation of styrenes: a profound influence of an
o-phenol. Journal of the American Chemical Society. [IF=2.573, Cited=28, 16448111].
- Gligorich KM, Schultz MJ, Sigman M (2006) Palladium(II)-catalyzed aerobic hydroalkoxylation of styrenes containing a
phenol. Journal of the American Chemical Society. [IF=2.573, Cited=24, 16506746].
- Miller JJ, Sigman M (2007) Design and synthesis of modular oxazoline ligands for the enantioselective chromium-catalyzed
addition of allyl bromide to ketones. Journal of the American Chemical Society. [IF=2.573, Cited=33, 17309263].
- Zhang Y, Sigman M (2007) Palladium(II)-catalyzed enantioselective aerobic dialkoxylation of 2-propenyl phenols: a
pronounced effect of copper additives on enantioselectivity. Journal of the American Chemical Society. [IF=2.573,
Cited=74, 17298071].
- Gligorich KM, Cummings SA, Sigman M (2007) Palladium-catalyzed reductive coupling of styrenes and organostannanes under
aerobic conditions. Journal of the American Chemical Society. [IF=2.573, Cited=33, 17963397].
- Pathak TP, Gligorich KM, Welm BE, Sigman M (2010) Synthesis and preliminary biological studies of 3-substituted indoles
accessed by a palladium-catalyzed enantioselective alkene difunctionalization reaction. Journal of the American Chemical
Society. [IF=2.573, Cited=80, 20486685].
- Liao L, Sigman M (2010) Palladium-catalyzed hydroarylation of 1,3-dienes with boronic esters via reductive formation of
pi-allyl palladium intermediates under oxidative conditions. Journal of the American Chemical Society. [IF=2.573,
Cited=31, 20608751].
- Anderson BJ, Keith JA, Sigman M (2010) Experimental and computational study of a direct O2-coupled Wacker oxidation:
water dependence in the absence of Cu salts. Journal of the American Chemical Society. [IF=2.573, Cited=24, 20687555].
- Werner EW, Sigman M (2010) A highly selective and general palladium catalyst for the oxidative Heck reaction of
electronically nonbiased olefins. Journal of the American Chemical Society. [IF=2.573, Cited=51, 20858011].
- Jensen KH, Webb JD, Sigman M (2010) Advancing the mechanistic understanding of an enantioselective palladium-catalyzed
alkene difunctionalization reaction. Journal of the American Chemical Society. [IF=2.573, Cited=58, 21082845].
- Liao L, Jana R, Urkalan KB, Sigman M (2011) A palladium-catalyzed three-component cross-coupling of conjugated dienes or
terminal alkenes with vinyl triflates and boronic acids. Journal of the American Chemical Society. [IF=2.573, Cited=74, 21449562].
- Michel BW, Steffens LD, Sigman M (2011) On the mechanism of the palladium-catalyzed tert-butylhydroperoxide-mediated
Wacker-type oxidation of alkenes using quinoline-2-oxazoline ligands. Journal of the American Chemical Society.
[IF=2.573, Cited=26, 21553838].
- Werner EW, Sigman M (2011) Operationally simple and highly (E)-styrenyl-selective Heck reactions of electronically
nonbiased olefins. Journal of the American Chemical Society. [IF=2.573, Cited=45, 21627305].
- DeLuca RJ, Sigman M (2011) Anti-Markovnikov hydroalkylation of allylic amine derivatives via a palladium-catalyzed
reductive cross-coupling reaction. Journal of the American Chemical Society. [IF=2.573, Cited=15, 21728336].
- Saini V, Sigman M (2012) Palladium-catalyzed 1,1-difunctionalization of ethylene. Journal of the American Chemical
Society. [IF=2.573, Cited=30, 22765909].
- Stokes BJ, Opra SM, Sigman M (2012) Palladium-catalyzed allylic cross-coupling reactions of primary and secondary
homoallylic electrophiles. Journal of the American Chemical Society. [IF=2.573, Cited=28, 22742056].
- McCammant MS, Liao L, Sigman M (2013) Palladium-catalyzed 1,4-difunctionalization of butadiene to form skipped polyenes.
Journal of the American Chemical Society. [IF=2.573, Cited=40, 23473452].
- Harper KC, Vilardi SC, Sigman M (2013) Prediction of catalyst and substrate performance in the enantioselective
propargylation of aliphatic ketones by a multidimensional model of steric effects. Journal of the American Chemical
Society. [IF=2.573, Cited=27, 23387331].
- Mei TS, Werner EW, Burckle AJ, Sigman M (2013) Enantioselective redox-relay oxidative heck arylations of acyclic alkenyl
alcohols using boronic acids. Journal of the American Chemical Society. [IF=2.573, Cited=84, 23607624].
- Xu L, Hilton MJ, Zhang X, ..., Wiest O (2014) Mechanism, reactivity, and selectivity in palladium-catalyzed redox-relay
Heck arylations of alkenyl alcohols. Journal of the American Chemical Society. [IF=2.573, Cited=69, 24410393].
- Bess EN, DeLuca RJ, Tindall DJ, ..., Sigman MS (2014) Analyzing site selectivity in Rh2(esp)2-catalyzed intermolecular
C-H amination reactions. Journal of the American Chemical Society. [IF=2.573, Cited=48, 24673332].
- Hickey DP, McCammant MS, Giroud F, ..., Minteer SD (2014) Hybrid enzymatic and organic electrocatalytic cascade for the
complete oxidation of glycerol. Journal of the American Chemical Society. [IF=2.573, Cited=33, 25350383].
- Saini V, O'Dair M, Sigman M (2015) Synthesis of highly functionalized tri- and tetrasubstituted alkenes via Pd-catalyzed
1,2-hydrovinylation of terminal 1,3-dienes. Journal of the American Chemical Society. [IF=2.573, Cited=26, 25555197].
- Patel HH, Sigman M (2015) Palladium-catalyzed enantioselective Heck alkenylation of acyclic alkenols using a redox-relay
strategy. Journal of the American Chemical Society. [IF=2.573, Cited=45, 25738548].
- Michel BW, Camelio AM, Cornell CN, Sigman M (2009) A general and efficient catalyst system for a Wacker-type oxidation
using TBHP as the terminal oxidant: application to classically challenging substrates. Journal of the American Chemical
Society. [IF=2.573, Cited=30, 19364100].
- Urkalan KB, Sigman M (2009) Palladium-catalyzed hydroalkylation of styrenes with organozinc reagents to form carbon-
carbon sp3-sp3 bonds under oxidative conditions. Journal of the American Chemical Society. [IF=2.573, Cited=20, 19929001].
- Jensen KH, Pathak TP, Zhang Y, Sigman M (2009) Palladium-catalyzed enantioselective addition of two distinct
nucleophiles across alkenes capable of quinone methide formation. Journal of the American Chemical Society. [IF=2.573,
Cited=54, 19902942].
- Miró J, Gensch T, Ellwart M, ..., Toste FD (2020) Enantioselective Allenoate-Claisen Rearrangement Using Chiral
Phosphate Catalysts. Journal of the American Chemical Society. [IF=2.573, Cited=9, 32182422].
- Rosales AR, Ross SP, Helquist P, ..., Wiest O (2020) Transition State Force Field for the Asymmetric Redox-Relay Heck
Reaction. Journal of the American Chemical Society. [IF=2.573, Cited=9, 32249569].
- Ross SP, Rahman AA, Sigman M (2020) Development and Mechanistic Interrogation of Interrupted Chain-Walking in the
Enantioselective Relay Heck Reaction. Journal of the American Chemical Society. [IF=2.573, Cited=10, 32412759].
- Werth J, Sigman M (2020) Connecting and Analyzing Enantioselective Bifunctional Hydrogen Bond Donor Catalysis Using Data
Science Tools. Journal of the American Chemical Society. [IF=2.573, Cited=12, 32844647].
- Levin MD, Ovian JM, Read JA, ..., Jacobsen EN (2020) Catalytic Enantioselective Synthesis of Difluorinated Alkyl
Bromides. Journal of the American Chemical Society. [IF=2.573, Cited=14, 32799536].
- Robinson SG, Wu X, Jiang B, ..., Lin S (2020) Mechanistic Studies Inform Design of Improved Ti(salen) Catalysts for
Enantioselective [3 + 2] Cycloaddition. Journal of the American Chemical Society. [IF=2.573, Cited=13, 33064948].
- Griffin JD, Pancoast AR, Sigman M (2021) Interrogation of 2,2'-Bipyrimidines as Low-Potential Two-Electron Electrolytes.
Journal of the American Chemical Society. [IF=2.573, Cited=4, 33411535].
- Saito M, Kawamata Y, Meanwell M, ..., Neurock M (2021) N-Ammonium Ylide Mediators for Electrochemical C-H
Oxidation. Journal of the American Chemical Society. [IF=2.573, Cited=19, 33983721].
- Dherange BD, Kelly PQ, Liles JP, ..., Levin MD (2021) Carbon Atom Insertion into Pyrroles and Indoles Promoted by
Chlorodiazirines. Journal of the American Chemical Society. [IF=2.573, Cited=21, 34286965].
- Yan Y, Robinson SG, Vaid TP, ..., Sanford MS (2021) Simultaneously Enhancing the Redox Potential and Stability of Multi-
Redox Organic Catholytes by Incorporating Cyclopropenium Substituents. Journal of the American Chemical Society.
[IF=2.573, Cited=7, 34387084].
- Zell D, Kingston C, Jermaks J, ..., Gosselin F (2021) Stereoconvergent and -divergent Synthesis of Tetrasubstituted
Alkenes by Nickel-Catalyzed Cross-Couplings. Journal of the American Chemical Society. [IF=2.573, Cited=5, 34735129].
- Dotson JJ, Anslyn EV, Sigman M (2021) A Data-Driven Approach to the Development and Understanding of Chiroptical Sensors
for Alcohols with Remote γ-Stereocenters. Journal of the American Chemical Society. [IF=2.573, Cited=5, 34735763].
- Gensch T, Dos Passos Gomes G, Friederich P, ..., Aspuru-Guzik A (2022) A Comprehensive Discovery Platform for
Organophosphorus Ligands for Catalysis. Journal of the American Chemical Society. [IF=2.573, Cited=41, 35020383].
- Cammarota RC, Liu W, Bacsa J, ..., Sigman M (2022) Mechanistically Guided Workflow for Relating Complex Reactive Site
Topologies to Catalyst Performance in C-H Functionalization Reactions. Journal of the American Chemical Society.
[IF=2.573, Cited=5, 35073072].
- Boni YT, Cammarota RC, Liao K, ..., Davies HML (2022) Leveraging Regio- and Stereoselective C(sp3)-H
Functionalization of Silyl Ethers to Train a Logistic Regression Classification Model for Predicting Site-Selectivity
Bias. Journal of the American Chemical Society. [IF=2.573, Cited=5, 35977100].
- Kelly SP, Shende VV, Flynn AR, ..., Sherman DH (2022) Data Science-Driven Analysis of Substrate-Permissive
Diketopiperazine Reverse Prenyltransferase NotF: Applications in Protein Engineering and Cascade Biocatalytic Synthesis
of (-)-Eurotiumin A. Journal of the American Chemical Society. [IF=2.573, Cited=4, 36223664].
- Xu EY, Werth J, Roos CB, ..., Knowles RR (2022) Noncovalent Stabilization of Radical Intermediates in the
Enantioselective Hydroamination of Alkenes with Sulfonamides. Journal of the American Chemical Society. [IF=2.573,
Cited=4, 36197450].
- Dotson JJ, van Dijk L, Timmerman JC, ..., Sigman M (2022) Data-Driven Multi-Objective Optimization Tactics for Catalytic
Asymmetric Reactions Using Bisphosphine Ligands. Journal of the American Chemical Society. [IF=2.573, Cited=10, 36574729].
- Tang T, Jones E, Wild T, ..., Sigman M (2022) Investigating Oxidative Addition Mechanisms of Allylic Electrophiles with
Low-Valent Ni/Co Catalysts Using Electroanalytical and Data Science Techniques. Journal of the American Chemical
Society. [IF=2.573, Cited=8, 36265077].
- Xu J, Grosslight S, Mack KA, ..., Gosselin F (2022) Atroposelective Negishi Coupling Optimization Guided by Multivariate
Linear Regression Analysis: Asymmetric Synthesis of KRAS G12C Covalent Inhibitor GDC-6036. Journal of the American
Chemical Society. [IF=2.573, Cited=8, 36326518].
- Tang T, Hazra A, Min DS, ..., Sigman M (2023) Interrogating the Mechanistic Features of Ni(I)-Mediated Aryl Iodide
Oxidative Addition Using Electroanalytical and Statistical Modeling Techniques. Journal of the American Chemical
Society. [IF=2.573, Cited=15, 37014945].
- Ortiz KG, Dotson JJ, Robinson DJ, ..., Karimov RR (2023) Catalyst-Controlled Enantioselective and Regiodivergent
Addition of Aryl Boron Nucleophiles to N-Alkyl Nicotinate Salts. Journal of the American Chemical Society. [IF=2.573,
Cited=3, 37205733].
- Clements HD, Flynn AR, Nicholls BT, ..., Sigman M (2023) Using Data Science for Mechanistic Insights and Selectivity
Predictions in a Non-Natural Biocatalytic Reaction. Journal of the American Chemical Society. [IF=2.573, Cited=3, 37530568].
- van Dijk L, Haas BC, Lim NK, ..., Sigman MS (2023) Data Science-Enabled Palladium-Catalyzed Enantioselective Aryl-
Carbonylation of Sulfonimidamides. Journal of the American Chemical Society. [IF=2.573, Cited=2, 37656964].
- Morack T, Myers TE, Karas LJ, ..., Miller SJ (2023) An Asymmetric Aromatic Finkelstein Reaction: A Platform for Remote
Diarylmethane Desymmetrization. Journal of the American Chemical Society. [IF=2.573, Cited=0, 37788150].
- Akana ME, Tcyrulnikov S, Akana-Schneider BD, ..., Weix DJ (2024) Computational Methods Enable the Prediction of Improved
Catalysts for Nickel-Catalyzed Cross-Electrophile Coupling. Journal of the American Chemical Society. [IF=2.573,
Cited=1, 38276910].
- Bartholomew GL, Kraus SL, Karas LJ, ..., Sarpong R (2024) 14N to 15N Isotopic Exchange of Nitrogen
Heteroaromatics through Skeletal Editing. Journal of the American Chemical Society. [IF=2.573, Cited=4, 38286797].
- Gao Y, Jiang B, Friede NC, ..., Reisman SE (2024) Electrocatalytic Asymmetric Nozaki-Hiyama-Kishi Decarboxylative
Coupling: Scope, Applications, and Mechanism. Journal of the American Chemical Society. [IF=2.573, Cited=0, 38324710].
- Haas BC, Lim NK, Jermaks J, ..., Sigman MS (2024) Enantioselective Sulfonimidamide Acylation via a Cinchona Alkaloid-
Catalyzed Desymmetrization: Scope, Data Science, and Mechanistic Investigation. Journal of the American Chemical
Society. [IF=2.573, Cited=0, 38480482].
- McFadden TP, Cope RB, Muhlestein R, ..., Sigman MS (2024) Using Data Science Tools to Reveal and Understand Subtle
Relationships of Inhibitor Structure in Frontal Ring-Opening Metathesis Polymerization. Journal of the American Chemical
Society. [IF=2.573, Cited=0, 38836636].
- Varenikov A, Gandelman M, Sigman M (2024) Development of Modular Nitrenium Bipolar Electrolytes for Possible
Applications in Symmetric Redox Flow Batteries. Journal of the American Chemical Society. [IF=2.573, Cited=0, 38963077].
- Mougel V, Santiago CB, Zhizhko PA, ..., Copéret C (2015) Quantitatively analyzing metathesis catalyst activity and
structural features in silica-supported tungsten imido-alkylidene complexes. Journal of the American Chemical Society.
[IF=2.573, Cited=23, 25938259].
- Zhang C, Santiago CB, Kou L, Sigman M (2015) Alkenyl carbonyl derivatives in enantioselective redox relay Heck
reactions: accessing α,β-unsaturated systems. Journal of the American Chemical Society. [IF=2.573, Cited=38, 26030059].
- Hickey DP, Schiedler DA, Matanovic I, ..., Sigman M (2015) Predicting Electrocatalytic Properties: Modeling Structure-
Activity Relationships of Nitroxyl Radicals. Journal of the American Chemical Society. [IF=2.573, Cited=32, 26635089].
- Zhang C, Santiago CB, Crawford JM, Sigman M (2015) Enantioselective Dehydrogenative Heck Arylations of Trisubstituted
Alkenes with Indoles to Construct Quaternary Stereocenters. Journal of the American Chemical Society. [IF=2.573,
Cited=44, 26624236].
- Neel AJ, Milo A, Sigman M, Toste FD (2016) Enantiodivergent Fluorination of Allylic Alcohols: Data Set Design Reveals
Structural Interplay between Achiral Directing Group and Chiral Anion. Journal of the American Chemical Society.
[IF=2.573, Cited=42, 26967114].
- Chen ZM, Hilton MJ, Sigman M (2016) Palladium-Catalyzed Enantioselective Redox-Relay Heck Arylation of 1,1-Disubstituted
Homoallylic Alcohols. Journal of the American Chemical Society. [IF=2.573, Cited=34, 27571167].
- Santiago CB, Milo A, Sigman M (2016) Developing a Modern Approach To Account for Steric Effects in Hammett-Type
Correlations. Journal of the American Chemical Society. [IF=2.573, Cited=22, 27652906].
- Patel HH, Sigman M (2016) Enantioselective Palladium-Catalyzed Alkenylation of Trisubstituted Alkenols To Form Allylic
Quaternary Centers. Journal of the American Chemical Society. [IF=2.573, Cited=32, 27768842].
- Yamamoto E, Hilton MJ, Orlandi M, ..., Sigman M (2016) Development and Analysis of a Pd(0)-Catalyzed Enantioselective
1,1-Diarylation of Acrylates Enabled by Chiral Anion Phase Transfer. Journal of the American Chemical Society.
[IF=2.573, Cited=37, 27960315].
- Race NJ, Schwalm CS, Nakamuro T, Sigman M (2016) Palladium-Catalyzed Enantioselective Intermolecular Coupling of Phenols
and Allylic Alcohols. Journal of the American Chemical Society. [IF=2.573, Cited=16, 27960316].
- Sevov CS, Hickey DP, Cook ME, ..., Sanford MS (2017) Physical Organic Approach to Persistent, Cyclable, Low-Potential
Electrolytes for Flow Battery Applications. Journal of the American Chemical Society. [IF=2.573, Cited=25, 28219237].
- Orlandi M, Coelho JAS, Hilton MJ, ..., Sigman M (2017) Parametrization of Non-covalent Interactions for Transition State
Interrogation Applied to Asymmetric Catalysis. Journal of the American Chemical Society. [IF=2.573, Cited=31, 28475315].
- Woods BP, Orlandi M, Huang CY, ..., Doyle AG (2017) Nickel-Catalyzed Enantioselective Reductive Cross-Coupling of
Styrenyl Aziridines. Journal of the American Chemical Society. [IF=2.573, Cited=51, 28406622].
- Plata RE, Hill DE, Haines BE, ..., Blackmond DG (2017) A Role for Pd(IV) in Catalytic Enantioselective C-H
Functionalization with Monoprotected Amino Acid Ligands under Mild Conditions. Journal of the American Chemical Society.
[IF=2.573, Cited=16, 28605190].
- Keylor MH, Niemeyer ZL, Sigman M, Tan KL (2017) Inverting Conventional Chemoselectivity in Pd-Catalyzed Amine Arylations
with Multiply Halogenated Pyridines. Journal of the American Chemical Society. [IF=2.573, Cited=10, 28715180].
- Mack JBC, Gipson JD, Du Bois J, ..., Sigman MS (2017) Ruthenium-Catalyzed C-H Hydroxylation in Aqueous Acid Enables
Selective Functionalization of Amine Derivatives. Journal of the American Chemical Society. [IF=2.573, Cited=26, 28660763].
- Orlandi M, Hilton MJ, Yamamoto E, ..., Sigman M (2017) Mechanistic Investigations of the Pd(0)-Catalyzed
Enantioselective 1,1-Diarylation of Benzyl Acrylates. Journal of the American Chemical Society. [IF=2.573, Cited=27, 28800230].
- Engl PS, Santiago CB, Gordon CP, ..., Togni A (2017) Exploiting and Understanding the Selectivity of Ru-N-Heterocyclic
Carbene Metathesis Catalysts for the Ethenolysis of Cyclic Olefins to α,ω-Dienes. Journal of the American Chemical
Society. [IF=2.573, Cited=10, 28820588].
- Niemeyer ZL, Pindi S, Khrakovsky DA, ..., Toste FD (2017) Parameterization of Acyclic Diaminocarbene Ligands Applied to
a Gold(I)-Catalyzed Enantioselective Tandem Rearrangement/Cyclization. Journal of the American Chemical Society.
[IF=2.573, Cited=15, 28885017].
- Bischoff AJ, Nelson BM, Niemeyer ZL, ..., Movassaghi M (2017) Quantitative Modeling of Bis(pyridine)silver(I)
Permanganate Oxidation of Hydantoin Derivatives: Guidelines for Predicting the Site of Oxidation in Complex Substrates.
Journal of the American Chemical Society. [IF=2.573, Cited=6, 28975782].
- Crawford JM, Stone EA, Metrano AJ, ..., Sigman MS (2018) Parameterization and Analysis of Peptide-Based Catalysts for
the Atroposelective Bromination of 3-Arylquinazolin-4(3H)-ones. Journal of the American Chemical Society. [IF=2.573,
Cited=18, 29300461].
- Patel HH, Prater MB, Squire SO, Sigman M (2018) Formation of Chiral Allylic Ethers via an Enantioselective Palladium-
Catalyzed Alkenylation of Acyclic Enol Ethers. Journal of the American Chemical Society. [IF=2.573, Cited=11, 29665329].
- Yuan Q, Sigman M (2018) Palladium-Catalyzed Enantioselective Relay Heck Arylation of Enelactams: Accessing
α,β-Unsaturated δ-Lactams. Journal of the American Chemical Society. [IF=2.573, Cited=18, 29746119].
- Mack JBC, Walker KL, Robinson SG, ..., Du Bois J (2019) Mechanistic Study of Ruthenium-Catalyzed C-H Hydroxylation
Reveals an Unexpected Pathway for Catalyst Arrest. Journal of the American Chemical Society. [IF=2.573, Cited=3, 30601662].
- Albright H, Riehl PS, McAtee CC, ..., Schindler CS (2019) Catalytic Carbonyl-Olefin Metathesis of Aliphatic Ketones:
Iron(III) Homo-Dimers as Lewis Acidic Superelectrophiles. Journal of the American Chemical Society. [IF=2.573,
Cited=19, 30596414].
- Hickey DP, Sandford C, Rhodes Z, ..., Minteer SD (2019) Investigating the Role of Ligand Electronics on Stabilizing
Electrocatalytically Relevant Low-Valent Co(I) Intermediates. Journal of the American Chemical Society. [IF=2.573,
Cited=16, 30599130].
- Allen JR, Bahamonde A, Furukawa Y, Sigman M (2019) Enantioselective N-Alkylation of Indoles via an Intermolecular Aza-
Wacker-Type Reaction. Journal of the American Chemical Society. [IF=2.573, Cited=12, 31117643].
- Kwon Y, Li J, Reid JP, ..., Miller SJ (2019) Disparate Catalytic Scaffolds for Atroposelective Cyclodehydration. Journal
of the American Chemical Society. [IF=2.573, Cited=26, 30920223].
- Bahamonde A, Al Rifaie B, Martín-Heras V, ..., Sigman M (2019) Enantioselective Markovnikov Addition of Carbamates to
Allylic Alcohols for the Construction of α-Secondary and α-Tertiary Amines. Journal of the American Chemical Society.
[IF=2.573, Cited=9, 31124676].
- Robinson SG, Yan Y, Hendriks KH, ..., Sigman M (2019) Developing a Predictive Solubility Model for Monomeric and
Oligomeric Cyclopropenium-Based Flow Battery Catholytes. Journal of the American Chemical Society. [IF=2.573, Cited=14, 31203608].
- Ferreira MAB, De Jesus Silva J, Grosslight S, ..., Copéret C (2019) Noncovalent Interactions Drive the Efficiency of
Molybdenum Imido Alkylidene Catalysts for Olefin Metathesis. Journal of the American Chemical Society. [IF=2.573,
Cited=7, 31180674].
- Christian AH, Jia S, Cao W, ..., Toste FD (2019) A Physical Organic Approach to Tuning Reagents for Selective and Stable
Methionine Bioconjugation. Journal of the American Chemical Society. [IF=2.573, Cited=20, 31361488].
- Yan Y, Robinson SG, Sigman M, Sanford MS (2019) Mechanism-Based Design of a High-Potential Catholyte Enables a 3.2 V
All-Organic Nonaqueous Redox Flow Battery. Journal of the American Chemical Society. [IF=2.573, Cited=14, 31503480].
- Sandford C, Fries LR, Ball TE, ..., Sigman M (2019) Mechanistic Studies into the Oxidative Addition of Co(I) Complexes:
Combining Electroanalytical Techniques with Parameterization. Journal of the American Chemical Society. [IF=2.573,
Cited=19, 31698896].
- Reid JP, Proctor RSJ, Sigman M, Phipps RJ (2019) Predictive Multivariate Linear Regression Analysis Guides Successful
Catalytic Enantioselective Minisci Reactions of Diazines. Journal of the American Chemical Society. [IF=2.573,
Cited=19, 31710210].
- Mandal SK, Jensen DR, Pugsley JS, Sigman M (2003) Scope of enantioselective palladium(II)-catalyzed aerobic alcohol
oxidations with (-)-sparteine. Journal of Organic Chemistry. [IF=0.885, Cited=16, 12762783].
- Mandal SK, Sigman M (2003) Palladium-catalyzed aerobic oxidative kinetic resolution of alcohols with an achiral
exogenous base. Journal of Organic Chemistry. [IF=0.885, Cited=13, 12968915].
- Schultz MJ, Hamilton SS, Jensen DR, Sigman M (2005) Development and comparison of the substrate scope of Pd-catalysts
for the aerobic oxidation of alcohols. Journal of Organic Chemistry. [IF=0.885, Cited=27, 15844968].
- Jensen KH, Sigman M (2010) Evaluation of catalyst acidity and substrate electronic effects in a hydrogen bond-catalyzed
enantioselective reaction. Journal of Organic Chemistry. [IF=0.885, Cited=16, 20919686].
- McCombs JR, Michel BW, Sigman M (2011) Catalyst-controlled Wacker-type oxidation of homoallylic alcohols in the absence
of protecting groups. Journal of Organic Chemistry. [IF=0.885, Cited=9, 21446720].
- Pathak TP, Sigman M (2011) Applications of ortho-quinone methide intermediates in catalysis and asymmetric synthesis.
Journal of Organic Chemistry. [IF=0.885, Cited=83, 21999240].
- DeLuca RJ, Edwards JL, Steffens LD, ..., Sigman M (2013) Wacker-type oxidation of internal alkenes using Pd(Quinox) and
TBHP. Journal of Organic Chemistry. [IF=0.885, Cited=16, 23363387].
- Harper KC, Sigman M (2013) Using physical organic parameters to correlate asymmetric catalyst performance. Journal of
Organic Chemistry. [IF=0.885, Cited=29, 23510194].
- Hilton MJ, Xu LP, Norrby PO, ..., Sigman M (2014) Investigating the nature of palladium chain-walking in the
enantioselective redox-relay Heck reaction of alkenyl alcohols. Journal of Organic Chemistry. [IF=0.885, Cited=43, 25186804].
- Sigman M, Miller JJ (2009) Examination of the role of Taft-type steric parameters in asymmetric catalysis. Journal of
Organic Chemistry. [IF=0.885, Cited=32, 19813764].
- Rajaram S, Sigman M (2002) Modular synthesis of amine-functionalized oxazolines. Organic Letters. [IF=1.091, Cited=11, 12323028].
- Jensen DR, Sigman M (2003) Palladium catalysts for aerobic oxidative kinetic resolution of secondary alcohols based on
mechanistic insight. Organic Letters. [IF=1.091, Cited=30, 12509891].
- Mercer GJ, Sigman M (2003) Diastereoselective synthesis of piperazines by manganese-mediated reductive cyclization.
Organic Letters. [IF=1.091, Cited=10, 12713331].
- Lee JY, Miller JJ, Hamilton SS, Sigman M (2005) Stereochemical diversity in chiral ligand design: discovery and
optimization of catalysts for the enantioselective addition of allylic halides to aldehydes. Organic Letters. [IF=1.091,
Cited=19, 15844919].
- Rajaram S, Sigman M (2005) Design of hydrogen bond catalysts based on a modular oxazoline template: application to an
enantioselective hetero Diels-Alder reaction. Organic Letters. [IF=1.091, Cited=28, 16288534].
- Balija AM, Stowers KJ, Schultz MJ, Sigman M (2006) Pd(II)-catalyzed conversion of styrene derivatives to acetals: impact
of (-)-sparteine on regioselectivity. Organic Letters. [IF=1.091, Cited=13, 16524283].
- Cornell CN, Sigman M (2006) Discovery of a practical direct O2-coupled Wacker oxidation with Pd[(-)-sparteine]Cl2.
Organic Letters. [IF=1.091, Cited=25, 16928088].
- Zhang Y, Sigman M (2006) Development of a general Pd(II)-catalyzed intermolecular hydroalkoxylation reaction of
vinylphenols by using a sacrificial alcohol as the hydride source. Organic Letters. [IF=1.091, Cited=13, 17107071].
- Gustafson JL, Sigman M, Sigman MS, ..., Miller SJ (2010) Linear free-energy relationship analysis of a catalytic
desymmetrization reaction of a diarylmethane-bis(phenol). Organic Letters. [IF=1.091, Cited=23, 20486656].
- Werner EW, Urkalan KB, Sigman M (2010) Pd(II)-catalyzed oxidative 1,1-diarylation of terminal olefins. Organic Letters.
[IF=1.091, Cited=32, 20481606].
- Pathak TP, Sigman M (2011) Palladium-catalyzed hydrofunctionalization of vinyl phenol derivatives with heteroaromatics.
Organic Letters. [IF=1.091, Cited=20, 21510631].
- Jana R, Pathak TP, Jensen KH, Sigman M (2012) Palladium(II)-catalyzed enantio- and diastereoselective synthesis of
pyrrolidine derivatives. Organic Letters. [IF=1.091, Cited=26, 22873944].
- DeLuca RJ, Sigman M (2012) The palladium-catalyzed anti-Markovnikov hydroalkylation of allylic alcohol derivatives.
Organic Letters. [IF=1.091, Cited=6, 23252845].
- Bess EN, Sigman M (2013) Distinctive meta-directing group effect for iridium-catalyzed 1,1-diarylalkene enantioselective
hydrogenation. Organic Letters. [IF=1.091, Cited=11, 23311924].
- Saini V, Liao L, Wang Q, ..., Sigman M (2013) Pd(0)-catalyzed 1,1-diarylation of ethylene and allylic carbonates.
Organic Letters. [IF=1.091, Cited=28, 24047468].
- Stokes BJ, Liao L, de Andrade AM, ..., Sigman M (2014) A palladium-catalyzed three-component-coupling strategy for the
differential vicinal diarylation of terminal 1,3-dienes. Organic Letters. [IF=1.091, Cited=32, 25162125].
- Podhajsky SM, Sigman M (2007) Coupling Pd-Catalyzed Alcohol Oxidation to Olefin Functionalization:
Hydrohalogenation/Hydroalkoxylation of Styrenes. Organometallics. [IF=0.776, Cited=17, 19779575].
- Milo A, Bess EN, Sigman M (2014) Interrogating selectivity in catalysis using molecular vibrations. Nature. [IF=11.591,
Cited=57, 24622199].
- Mei TS, Patel HH, Sigman M (2014) Enantioselective construction of remote quaternary stereocentres. Nature. [IF=11.591,
Cited=125, 24717439].
- Neel AJ, Hilton MJ, Sigman M, Toste FD (2017) Exploiting non-covalent π interactions for catalyst design. Nature.
[IF=11.591, Cited=163, 28358089].
- Wheeldon I, Minteer SD, Banta S, ..., Sigman M (2016) Substrate channelling as an approach to cascade reactions. Nature
Chemistry. [IF=3.667, Cited=170, 27001725].
- Niemeyer ZL, Milo A, Hickey DP, Sigman M (2016) Parameterization of phosphine ligands reveals mechanistic pathways and
predicts reaction outcomes. Nature Chemistry. [IF=3.667, Cited=59, 27219707].
- Sheng H, Sun J, Rodríguez O, ..., Liu C (2024) Autonomous closed-loop mechanistic investigation of molecular
electrochemistry via automation. Nature Communications. [IF=3.268, Cited=0, 38555303].
- Liu J, Yuan Q, Toste FD, Sigman M (2019) Enantioselective construction of remote tertiary carbon-fluorine bonds. Nature
Chemistry. [IF=3.667, Cited=15, 31308495].
- Reid JP, Sigman M (2019) Holistic prediction of enantioselectivity in asymmetric catalysis. Nature. [IF=11.591,
Cited=60, 31316193].
- Gnaim S, Bauer A, Zhang HJ, ..., Sigman M (2022) Cobalt-electrocatalytic HAT for functionalization of unsaturated C-C
bonds. Nature. [IF=11.591, Cited=19, 35614246].
- Christensen M, Yunker LPE, Adedeji F, ..., Hein JE (2021) Data-science driven autonomous process optimization.
Communications Chemistry. [IF=1.295, Cited=25, 36697524].
- Sigman M, Schultz MJ (2004) The renaissance of palladium(II)-catalyzed oxidation chemistry. Organic and Biomolecular
Chemistry. [IF=0.77, Cited=37, 15351815].
- Stokes BJ, Bischoff AJ, Sigman M (2014) Pd(Quinox)-Catalyzed Allylic Relay Suzuki Reactions of Secondary Homostyrenyl
Tosylates via Alkene-Assisted Oxidative Addition. Chemical Science. [IF=1.563, Cited=10, 24910768].
- McCammant MS, Sigman M (2015) Development and Investigation of a Site Selective Palladium-Catalyzed
1,4-Difunctionalization of Isoprene using Pyridine-Oxazoline Ligands. Chemical Science. [IF=1.563, Cited=22, 25705367].
- Zhang C, Tutkowski B, DeLuca RJ, ..., Sigman M (2016) Palladium-Catalyzed Enantioselective Heck Alkenylation of
Trisubstituted Allylic Alkenols: A Redox-Relay Strategy to Construct Vicinal Stereocenters. Chemical Science. [IF=1.563,
Cited=8, 28435657].
- Bess EN, Guptill DM, Davies HML, Sigman M (2015) Using IR vibrations to quantitatively describe and predict site-
selectivity in multivariate Rh-catalyzed C-H functionalization. Chemical Science. [IF=1.563, Cited=17, 29403640].
- Weldy NM, Schafer AG, Owens CP, ..., Blakey SB (2016) Iridium(iii)-bis(imidazolinyl)phenyl catalysts for
enantioselective C-H functionalization with ethyl diazoacetate. Chemical Science. [IF=1.563, Cited=13, 29997805].
- Thornbury RT, Saini V, Fernandes TdA, ..., Toste FD (2017) The development and mechanistic investigation of a palladium-
catalyzed 1,3-arylfluorination of chromenes. Chemical Science. [IF=1.563, Cited=14, 28451354].
- Macazo FC, Hickey DP, Abdellaoui S, ..., Minteer SD (2017) Polymer-immobilized, hybrid multi-catalyst architecture for
enhanced electrochemical oxidation of glycerol. Chemical Communications. [IF=0.902, Cited=4, 28871300].
- Lancaster L, Hickey DP, Sigman M, ..., Wheeldon I (2018) Bioinspired design of a hybrid bifunctional enzymatic/organic
electrocatalyst for site selective alcohol oxidation. Chemical Communications. [IF=0.902, Cited=1, 29260808].
- Santiago CB, Guo JY, Sigman M (2018) Predictive and mechanistic multivariate linear regression models for reaction
development. Chemical Science. [IF=1.563, Cited=90, 29719711].
- Metsänen TT, Lexa KW, Santiago CB, ..., Sigman M (2018) Combining traditional 2D and modern physical organic-derived
descriptors to predict enhanced enantioselectivity for the key aza-Michael conjugate addition in the synthesis of
Prevymis™ (letermovir). Chemical Science. [IF=1.563, Cited=6, 30210766].
- Coelho JAS, Matsumoto A, Orlandi M, ..., Toste FD (2018) Enantioselective fluorination of homoallylic alcohols enabled
by the tuning of non-covalent interactions. Chemical Science. [IF=1.563, Cited=7, 30310638].
- Hananya N, Reid JP, Green O, ..., Shabat D (2018) Rapid chemiexcitation of phenoxy-dioxetane luminophores yields
ultrasensitive chemiluminescence assays. Chemical Science. [IF=1.563, Cited=18, 30809354].
- Sandford C, Edwards MA, Klunder KJ, ..., Minteer SD (2019) A synthetic chemist's guide to electroanalytical tools for
studying reaction mechanisms. Chemical Science. [IF=1.563, Cited=61, 31367303].
- Chen ZM, Liu J, Guo JY, ..., Sigman M (2019) Palladium-catalyzed enantioselective alkenylation of alkenylbenzene
derivatives. Chemical Science. [IF=1.563, Cited=5, 31588293].
- Reid JP, Hu M, Ito S, ..., Toste FD (2020) Strategies for remote enantiocontrol in chiral gold(iii) complexes applied to
catalytic enantioselective γ,δ-Diels-Alder reactions. Chemical Science. [IF=1.563, Cited=6, 34094110].
- De Jesus Silva J, Ferreira MAB, Fedorov A, ..., Copéret C (2020) Molecular-level insight in supported olefin metathesis
catalysts by combining surface organometallic chemistry, high throughput experimentation, and data analysis. Chemical
Science. [IF=1.563, Cited=3, 33133485].
- Tang T, Sandford C, Minteer SD, Sigman M (2021) Analyzing mechanisms in Co(i) redox catalysis using a pattern
recognition platform. Chemical Science. [IF=1.563, Cited=6, 34168755].
- DeLano TJ, Dibrell SE, Lacker CR, ..., Reisman SE (2021) Nickel-catalyzed asymmetric reductive cross-coupling of
α-chloroesters with (hetero)aryl iodides. Chemical Science. [IF=1.563, Cited=12, 34168828].
- Pancoast AR, McCormack SL, Galinat S, ..., Sigman M (2023) Data science enabled discovery of a highly soluble
2,2'-bipyrimidine anolyte for application in a flow battery. Chemical Science. [IF=1.563, Cited=0, 38075655].
- Jett B, Flynn A, Sigman M, Sanford MS (2023) Identifying structure-function relationships to modulate crossover in
nonaqueous redox flow batteries. Journal of Materials Chemistry A. [IF=1.637, Cited=0, 38213509].
- Kilgallon LJ, McFadden TP, Sigman M, Johnson JA (2024) Tricyclononenes and tricyclononadienes as efficient monomers for
controlled ROMP: understanding structure-propagation rate relationships and enabling facile post-polymerization
modification. Chemical Science. [IF=1.563, Cited=0, 38846402].
- Crawford JM, Sigman M (2019) Conformational Dynamics in Asymmetric Catalysis: Is Catalyst Flexibility a Design Element?
Synthesis. [IF=0.648, Cited=27, 31235980].
- Harper KC, Sigman M (2011) Predicting and optimizing asymmetric catalyst performance using the principles of
experimental design and steric parameters. Proceedings of the National Academy of Sciences of the United States of
America. [IF=2.765, Cited=33, 21262844].
- Bess EN, Bischoff AJ, Sigman M (2014) Designer substrate library for quantitative, predictive modeling of reaction
performance. Proceedings of the National Academy of Sciences of the United States of America. [IF=2.765, Cited=27, 25267648].
- Haas BC, Goetz AE, Bahamonde A, ..., Sigman M (2022) Predicting relative efficiency of amide bond formation using
multivariate linear regression. Proceedings of the National Academy of Sciences of the United States of America.
[IF=2.765, Cited=8, 35412905].
- Samha MH, Karas LJ, Vogt DB, ..., Sigman M (2024) Predicting success in Cu-catalyzed C-N coupling reactions using data
science. Science advances. [IF=2.861, Cited=0, 38232169].
- Harper KC, Sigman M (2011) Three-dimensional correlation of steric and electronic free energy relationships guides
asymmetric propargylation. Science. [IF=7.729, Cited=65, 21960632].
- Werner EW, Mei TS, Burckle AJ, Sigman M (2012) Enantioselective Heck arylations of acyclic alkenyl alcohols using a
redox-relay strategy. Science. [IF=7.729, Cited=128, 23239733].
- Milo A, Neel AJ, Toste FD, Sigman M (2015) Organic chemistry. A data-intensive approach to mechanistic elucidation
applied to chiral anion catalysis. Science. [IF=7.729, Cited=79, 25678656].
- Zhao S, Gensch T, Murray B, ..., Biscoe MR (2018) Enantiodivergent Pd-catalyzed C-C bond formation enabled through
ligand parameterization. Science. [IF=7.729, Cited=38, 30237245].
- Newman-Stonebraker SH, Smith SR, Borowski JE, ..., Doyle AG (2021) Univariate classification of phosphine ligation state
and reactivity in cross-coupling catalysis. Science. [IF=7.729, Cited=28, 34648340].
- Nistanaki SK, Williams CG, Wigman B, ..., Nelson HM (2022) Catalytic asymmetric C-H insertion reactions of vinyl
carbocations. Science. [IF=7.729, Cited=8, 36480623].
- Rein J, Rozema SD, Langner OC, ..., Lin S (2023) Generality-oriented optimization of enantioselective aminoxyl radical
catalysis. Science. [IF=7.729, Cited=9, 37200427].
- Ridges S, Heaton WL, Joshi D, ..., Trede NS (2012) Zebrafish screen identifies novel compound with selective toxicity
against leukemia. Blood. [IF=2.983, Cited=100, 22490804].
- Vaden RM, Gligorich KM, Jana R, ..., Welm BE (2014) The small molecule C-6 is selectively cytotoxic against breast
cancer cells and its biological action is characterized by mitochondrial defects and endoplasmic reticulum stress.
Breast Cancer Research. [IF=1.764, Cited=2, 25425314].
- Sigman M, Jensen DR, Rajaram S (2002) Catalytic enantioselective oxidations using molecular oxygen. None. [IF=None,
Cited=0, 12478717].
- Michel BW, Sigman M (2011) Peroxide-Mediated Wacker Oxidations for Organic Synthesis. Aldrichimica Acta. [IF=0.515,
Cited=0, 27746479].
Publication with MISMATCHING institution:
- Sigman M, Sena R (1993) Pretend play in high-risk and developmentally delayed children. None. [IF=None, Cited=1, 7683392].
- Sigman M (1993) Laboratory testing in the evaluation of male infertility. A rational approach. World Journal of Urology.
[IF=1.435, Cited=2, 8343801].
- Barttfeld P, Abboud S, Lagercrantz H, ..., Dehaene-Lambertz G (2018) A lateral-to-mesial organization of human ventral
visual cortex at birth. Brain Structure and Function. [IF=0.955, Cited=10, 29752588].
- Sigman M, Lönnerdal B (1990) Relationship of milk iron and the changing concentration of mammary tissue transferrin
receptors during the course of lactation. Journal of Nutritional Biochemistry. [IF=1.201, Cited=4, 15539176].
- Sigman M, Lönnerdal B (1990) Characterization of transferrin receptors on plasma membranes of lactating rat mammary
tissue. Journal of Nutritional Biochemistry. [IF=1.201, Cited=4, 15539210].
- Sigman M, Jarow JP (1997) Endocrine evaluation of infertile men. Urology. [IF=0.983, Cited=52, 9372871].
- Sigman M, Jobert A, Lebihan D, Dehaene S (2007) Parsing a sequence of brain activations at psychological times using
fMRI. NeuroImage. [IF=1.782, Cited=20, 17275341].
- Sigman M, Neumann C, Baksh M, ..., McDonald MA (1989) Relationship between nutrition and development in Kenyan toddlers.
Journal of Pediatrics. [IF=1.32, Cited=37, 2769494].
- Sigman M, Lopes L (1993) The correlation between round cells and white blood cells in the semen. Journal of Urology.
[IF=2.411, Cited=9, 8479031].
- Sigman M, Laudone VP, Jenkins AD, ..., Walker RD (1987) Initial experience with extracorporeal shock wave lithotripsy in
children. Journal of Urology. [IF=2.411, Cited=36, 3656542].
- Sigman M, Siegel DJ (1992) The interface between the psychobiological and cognitive models of attachment. Behavioral and
Brain Sciences. [IF=0.448, Cited=1, 24924042].
- Sigman M, Ma CY, Ilgner RH (2001) Performance evaluation of an in-injection port thermal desorption/gas
chromatographic/negative ion chemical ionization mass spectrometric method for trace explosive vapor analysis.
Analytical Chemistry. [IF=1.41, Cited=9, 11248894].
- Sigman M, Ma CY (1999) In-injection port thermal desorption for explosives trace evidence analysis. Analytical
Chemistry. [IF=1.41, Cited=16, 21662844].
- Sigman M, Gilbert CD (2000) Learning to find a shape. Nature Neuroscience. [IF=4.893, Cited=89, 10700259].
- Mundy P, Kasari C, Sigman M, Ruskin E (1995) Nonverbal communication and early language acquisition in children with
Down syndrome and in normally developing children. None. [IF=None, Cited=65, 7537345].
- Cecchi GA, Sigman M, Alonso JM, ..., Magnasco MO (2000) Noise in neurons is message dependent. Proceedings of the
National Academy of Sciences of the United States of America. [IF=2.765, Cited=57, 10792057].
- Sigman M, Cecchi GA, Gilbert CD, Magnasco MO (2001) On a common circle: natural scenes and Gestalt rules. Proceedings of
the National Academy of Sciences of the United States of America. [IF=2.765, Cited=136, 11172054].
- Sigman M (1998) Schizophrenia and severe affective illness alternating over time in some patients: a hypothesis.
Psychiatry (New York). [IF=0.95, Cited=2, 9823035].
- Siller M, Hotez E, Swanson M, ..., Sigman M (2018) Parent coaching increases the parents' capacity for reflection and
self-evaluation: results from a clinical trial in autism. Attachment and Human Development. [IF=1.697, Cited=13, 29513132].
- Sigman M, Lönnerdal B (1990) Response of rat mammary gland transferrin receptors to maternal dietary iron during
pregnancy and lactation. American Journal of Clinical Nutrition. [IF=2.07, Cited=18, 2393007].
- Sigman M, Ruskin E, Arbeile S, ..., Zierhut C (1999) Continuity and change in the social competence of children with
autism, Down syndrome, and developmental delays. Monographs of the Society for Research in Child Development. [IF=4.43,
Cited=187, 10412222].
- Dere E, Huse S, Hwang K, ..., Boekelheide K (2016) Intra- and inter-individual differences in human sperm DNA
methylation. Andrology. [IF=1.338, Cited=7, 27089098].
- Bianchi E, Stermer A, Boekelheide K, ..., Hwang K (2018) High-quality human and rat spermatozoal RNA isolation for
functional genomic studies. Andrology. [IF=1.338, Cited=12, 29470852].
- Sigman M, McDonald MA, Neumann C, Bwibo N (1991) Prediction of cognitive competence in Kenyan children from Toddler
nutrition, family characteristics and abilities. Journal of Child Psychology and Psychiatry and Allied Disciplines.
[IF=3.012, Cited=36, 1903401].
- Sigman M (1996) Resistances in a hospital setting: issues in resolution. American Journal of Psychotherapy. [IF=0.701,
Cited=2, 8867578].
- Hassan S, Cinq-Mars C, Sigman M (2000) Conflict in group therapy of chronic schizophrenics: coping with aggression.
American Journal of Psychotherapy. [IF=0.701, Cited=2, 10928247].
- Kashiwa HK, Sigman M (1966) Calcium localized in odontogenic cells of rat mandibular teeth by the glyoxal bis
(2-hydroxyanil) method. Journal of Dental Research. [IF=2.303, Cited=24, 4163588].
- Sigman M, Arbelle S, Dissanayake C (1995) Current research findings on childhood autism. Canadian Journal of Psychiatry.
[IF=1.805, Cited=6, 7585397].
- Robinson HM, Sigman M, Wilson JP (1997) Duty-related stressors and PTSD symptoms in suburban police officers.
Psychological Reports. [IF=1.147, Cited=33, 9400075].
- Sigman M (1991) A guide to assisted reproductive techniques. None. [IF=None, Cited=0, 10148063].
- Sigman M, Ma CY (2001) Detection limits for GC/MS analysis of organic explosives. Journal of Forensic Sciences.
[IF=0.931, Cited=0, 11210925].
- Sigman M, Kasari C, Kwon JH, Yirmiya N (1992) Responses to the negative emotions of others by autistic, mentally
retarded, and normal children. Child Development. [IF=2.441, Cited=0, 1505241].
- Sigman M (1991) Assisted reproductive technics for the treatment of male factor infertility. None. [IF=None, Cited=0, 1763277].
- Sigman M (1990) Referral barriers--near failure to thrive of a group. None. [IF=None, Cited=0, 2326386].
- Sigman M, Neumann C, Jansen AA, Bwibo N (1989) Cognitive abilities of Kenyan children in relation to nutrition, family
characteristics, and education. Child Development. [IF=2.441, Cited=0, 2515042].
- Sigman M, Burke KI, Swarner OW, Shavlik GW (1989) Effects of microwaving human milk: changes in IgA content and
bacterial count. None. [IF=None, Cited=0, 2723294].
- Sigman M (1994) Assisted reproductive techniques and male infertility. Urologic Clinics of North America. [IF=1.04,
Cited=0, 8059504].
- Sigman M, Jarow JP (1997) Ipsilateral testicular hypotrophy is associated with decreased sperm counts in infertile men
with varicoceles. Journal of Urology. [IF=2.411, Cited=0, 9224376].
- Sigman M (1997) Male infertility. None. [IF=None, Cited=0, 9433070].
- Sigman M (1998) The Emanuel Miller Memorial Lecture 1997. Change and continuity in the development of children with
autism. Journal of Child Psychology and Psychiatry and Allied Disciplines. [IF=3.012, Cited=0, 9758191].
Publication with MISSING institution:
- Sigman M, Parmelee AH (1977) Child psychology, 1877. None. [IF=None, Cited=0, 329669].
- Jensen DR, Schultz MJ, Mueller JA, Sigman M (2003) A well-defined complex for palladium-catalyzed aerobic oxidation of
alcohols: design, synthesis, and mechanistic considerations. Angewandte Chemie - International Edition. [IF=2.456,
Cited=61, 12923852].
- Gligorich KM, Sigman M (2006) Mechanistic questions about the reaction of molecular oxygen with palladium in oxidase
catalysis. Angewandte Chemie - International Edition. [IF=2.456, Cited=35, 16986187].
- Jensen KH, Sigman M (2007) Systematically probing the effect of catalyst acidity in a hydrogen-bond-catalyzed
enantioselective reaction. Angewandte Chemie - International Edition. [IF=2.456, Cited=27, 17503406].
- Miller JJ, Sigman M (2008) Quantitatively correlating the effect of ligand-substituent size in asymmetric catalysis
using linear free energy relationships. Angewandte Chemie - International Edition. [IF=2.456, Cited=28, 18069711].
- Iwai Y, Gligorich KM, Sigman M (2008) Aerobic alcohol oxidation coupled to palladium-catalyzed alkene hydroarylation
with boronic esters. Angewandte Chemie - International Edition. [IF=2.456, Cited=26, 18348123].
- Urkalan KB, Sigman M (2009) Palladium-catalyzed oxidative intermolecular difunctionalization of terminal alkenes with
organostannanes and molecular oxygen. Angewandte Chemie - International Edition. [IF=2.456, Cited=64, 19308939].
- Michel BW, McCombs JR, Winkler A, Sigman M (2010) Catalyst-controlled Wacker-type oxidation of protected allylic amines.
Angewandte Chemie - International Edition. [IF=2.456, Cited=15, 20799310].
- Saini V, Stokes BJ, Sigman M (2013) Transition-metal-catalyzed laboratory-scale carbon-carbon bond-forming reactions of
ethylene. Angewandte Chemie - International Edition. [IF=2.456, Cited=27, 24105881].
- Sigman M, Mundy P (1987) Symbolic processes in young autistic children. None. [IF=None, Cited=2, 2441320].
- Kopp CB, Sigman M, Parmelee AH, Jeffrey WE (1975) Neurological organization and visual fixation in infants at 40 weeks
conceptional age. Developmental Psychobiology. [IF=0.735, Cited=14, 1225691].
- Beckwith L, Sigman M, Cohen SE, Parmelee AH (1977) Vocal output in preterm infants. Developmental Psychobiology.
[IF=0.735, Cited=5, 563823].
- Caplan R, Guthrie D, Komo S, ..., Sigman M (1999) Infantile spasms: facial expression of affect before and after
epilepsy surgery. Brain and Cognition. [IF=0.998, Cited=0, 10079120].
- Mark HF, Bai H, Sotomayor E, ..., Sigman M (1999) A variant Klinefelter syndrome patient with an XXY/XX/XY karyotype
studied by GTG-banding and fluorescence in situ hybridization. Experimental and Molecular Pathology. [IF=0.768,
Cited=11, 10493892].
- Mark HF, Sigman M (1999) Male infertility associated with a unique 8;22 translocation. Experimental and Molecular
Pathology. [IF=0.768, Cited=5, 10493893].
- Sigman M, Erdynast A (1988) Interpersonal understanding and moral judgment in adolescents with emotional and cognitive
disorders. Child Psychiatry and Human Development. [IF=1.292, Cited=1, 3229152].
- Sigman M, Amit Z (1983) Cognitive inhibition of human gastric acid output--studies using telemetric measurements.
Journal of Behavioral Medicine. [IF=1.248, Cited=0, 6352952].
- Kasari C, Sigman M, Mundy P, Yirmiya N (1988) Caregiver interactions with autistic children. None. [IF=None, Cited=56, 2966189].
- Sigman M, Ungerer JA, Russell A (1983) Moral judgment in relation to behavioral and cognitive disorders in adolescents.
None. [IF=None, Cited=4, 6655150].
- Sigman M, Ungerer J (1981) Sensorimotor skills and language comprehension in autistic children. None. [IF=None,
Cited=18, 7276397].
- Mundy P, Sigman M, Ungerer J, Sherman T (1987) Nonverbal communication and play correlates of language development in
autistic children. Journal of Autism and Developmental Disorders. [IF=1.863, Cited=81, 3654487].
- Ungerer JA, Sigman M (1987) Categorization skills and receptive language development in autistic children. Journal of
Autism and Developmental Disorders. [IF=1.863, Cited=34, 3571142].
- Bristol MM, Cohen DJ, Costello EJ, ..., Spence MA (1996) State of the science in autism: report to the National
Institutes Health. Journal of Autism and Developmental Disorders. [IF=1.863, Cited=43, 8744475].
- Yirmiya N, Sigman M, Freeman BJ (1994) Comparison between diagnostic instruments for identifying high-functioning
children with autism. Journal of Autism and Developmental Disorders. [IF=1.863, Cited=22, 8050982].
- Arbelle S, Sigman M, Kasari C (1994) Compliance with parental prohibition in autistic children. Journal of Autism and
Developmental Disorders. [IF=1.863, Cited=9, 7844094].
- Kasari C, Sigman M, Mundy P, Yirmiya N (1990) Affective sharing in the context of joint attention interactions of
normal, autistic, and mentally retarded children. Journal of Autism and Developmental Disorders. [IF=1.863, Cited=158, 2139025].
- Mundy P, Sigman M, Kasari C (1990) A longitudinal study of joint attention and language development in autistic
children. Journal of Autism and Developmental Disorders. [IF=1.863, Cited=351, 2324051].
- Sigman M, Ungerer JA (1984) Attachment behaviors in autistic children. Journal of Autism and Developmental Disorders.
[IF=1.863, Cited=57, 6207163].
- Mann SM, Wang NJ, Liu DH, ..., Schanen NC (2004) Supernumerary tricentric derivative chromosome 15 in two boys with
intractable epilepsy: another mechanism for partial hexasomy. Human Genetics. [IF=1.653, Cited=25, 15141347].
- Sigman M, Amit Z (1982) Progressive relaxation exercises and human gastric acid output--a study using telemetric
measurements. Behaviour Research and Therapy. [IF=1.66, Cited=1, 7159356].
- Sigman M, Coles P (1980) Visual scanning during pattern recognition in children and adults. Journal of Experimental
Child Psychology. [IF=1.266, Cited=2, 7430944].
- Cohen SE, Parmelee AH, Sigman M, Beckwith L (1982) Neonatal risk factors in preterm infants. None. [IF=None, Cited=5, 6184017].
- Gligorich KM, Iwai Y, Cummings SA, Sigman M (2009) A new approach to carbon-carbon bond formation: Development of
aerobic Pd-catalyzed reductive coupling reactions of organometallic reagents and styrenes. Tetrahedron. [IF=0.579,
Cited=10, 20161306].
- Podhajsky SM, Iwai Y, Cook-Sneathen A, Sigman M (2011) Asymmetric palladium-catalyzed hydroarylation of styrenes and
dienes. Tetrahedron. [IF=0.579, Cited=21, 21743752].
- Pathak TP, Osiak JG, Vaden RM, ..., Sigman M (2012) Synthesis and Preliminary Biological Study of Bisindolylmethanes
Accessed by an Acid-Catalyzed Hydroarylation of Vinylindoles. Tetrahedron. [IF=0.579, Cited=9, 22778488].
- Ungerer JA, Sigman M (1981) Symbolic play and language comprehension in autistic children. None. [IF=None, Cited=104, 6167603].
- Enquist E, Stein BS, Sigman M (1994) Laparoscopic versus subinguinal varicocelectomy: a comparative study. Fertility and
Sterility. [IF=2.092, Cited=25, 8194623].
- Beckwith L, Rozga A, Sigman M (2002) Maternal sensitivity and attachment in atypical groups. None. [IF=None, Cited=7, 12402676].
- Jarow JP, Oates RD, Buch JP, ..., Sigman M (1997) Effect of level of anastomosis and quality of intraepididymal sperm on
the outcome of end-to-side epididymovasostomy. Urology. [IF=0.983, Cited=11, 9111630].
- Jarow JP, Coburn M, Sigman M (1996) Incidence of varicoceles in men with primary and secondary infertility. Urology.
[IF=0.983, Cited=73, 8560666].
- Kennedy MA, Sama AE, Sigman M (2000) Tibiofibular syndesmosis and ossification. Case report: sequelae of ankle sprain in
an adolescent football player. Journal of Emergency Medicine. [IF=0.72, Cited=9, 10699529].
- Gilbert CD, Sigman M, Crist RE (2001) The neural basis of perceptual learning. Neuron. [IF=3.346, Cited=399, 11567610].
- Mack JBC, Gipson JD, Du Bois J, ..., Sigman MS (2021) Correction to "Ruthenium-Catalyzed C-H Hydroxylation in Aqueous
Acid Enables Selective Functionalization of Amine Derivatives". Journal of the American Chemical Society. [IF=2.573,
Cited=1, 33570914].
- Woods BP, Orlandi M, Huang CYD, ..., Doyle AG (2018) Correction to "Nickel-Catalyzed Enantioselective Reductive Cross-
Coupling of Styrenyl Aziridines". Journal of the American Chemical Society. [IF=2.573, Cited=1, 29889505].
- Engl PS, Santiago CB, Gordon CP, ..., Togni A (2018) Correction to "Exploiting and Understanding the Selectivity of Ru-
N-Heterocyclic Carbene Metathesis Catalysts for the Ethenolysis of Cyclic Olefins to α,ω-Dienes". Journal of the
American Chemical Society. [IF=2.573, Cited=0, 30543408].
- Allen JR, Bahamonde A, Furukawa Y, Sigman M (2019) Correction to "Enantioselective N-Alkylation of Indoles via an
Intermolecular Aza-Wacker-Type Reaction". Journal of the American Chemical Society. [IF=2.573, Cited=0, 31347841].
- Hickey DP, Sandford C, Rhodes Z, ..., Minteer SD (2019) Correction to "Investigating the Role of Ligand Electronics on
Stabilizing Electrocatalytically Relevant Low-Valent Co(I) Intermediates". Journal of the American Chemical Society.
[IF=2.573, Cited=0, 31525919].
- Travis L, Sigman M, Ruskin E (2001) Links between social understanding and social behavior in verbally able children
with autism. Journal of Autism and Developmental Disorders. [IF=1.863, Cited=58, 11450811].
- Kasari C, Sigman M (1997) Linking parental perceptions to interactions in young children with autism. Journal of Autism
and Developmental Disorders. [IF=1.863, Cited=100, 9018581].
- Lefkowitz ES, Romo LF, Corona R, ..., Sigman M (2000) How Latino American and European American adolescents discuss
conflicts, sexuality, and AIDS with their mothers. Developmental Psychology. [IF=1.688, Cited=20, 10830976].
- O'Connor MJ, Sigman M, Brill N (1987) Disorganization of attachment in relation to maternal alcohol consumption. Journal
of Consulting and Clinical Psychology. [IF=2.356, Cited=26, 3693649].
- Capps L, Kasari C, Yirmiya N, Sigman M (1993) Parental perception of emotional expressiveness in children with autism.
Journal of Consulting and Clinical Psychology. [IF=2.356, Cited=62, 8326050].
- Whaley SE, Pinto A, Sigman M (1999) Characterizing interactions between anxious mothers and their children. Journal of
Consulting and Clinical Psychology. [IF=2.356, Cited=170, 10596505].
- Harper KC, Bess EN, Sigman M (2012) Multidimensional steric parameters in the analysis of asymmetric catalytic
reactions. Nature Chemistry. [IF=3.667, Cited=79, 22522256].
- Powell CR, Desai RA, Makhlouf AA, ..., Niederberger CS (2007) Computational models for detection of endocrinopathy in
subfertile males. International Journal of Impotence Research. [IF=1.233, Cited=2, 17717523].
- Schultz MJ, Park CC, Sigman M (2002) A convenient palladium-catalyzed aerobic oxidation of alcohols at room temperature.
Chemical Communications. [IF=0.902, Cited=28, 12536803].
- Jensen KH, Sigman M (2008) Mechanistic approaches to palladium-catalyzed alkene difunctionalization reactions. Organic
and Biomolecular Chemistry. [IF=0.77, Cited=140, 18972034].
- Gligorich KM, Sigman M (2009) Recent advancements and challenges of palladium(II)-catalyzed oxidation reactions with
molecular oxygen as the sole oxidant. Chemical Communications. [IF=0.902, Cited=71, 19662234].
- Stansbury K, Sigman M (2000) Responses of preschoolers in two frustrating episodes: emergence of complex strategies for
emotion regulation. Journal of Genetic Psychology. [IF=0.747, Cited=38, 10851681].
- Cohen SE, Parmelee AH, Sigman M, Beckwith L (1988) Antecedents of school problems in children born preterm. Journal of
Pediatric Psychology. [IF=1.269, Cited=4, 3216272].
- Sigman M, Cohen SE, Beckwith L, Parmelee AH (1981) Social and familial influences on the development of preterm infants.
Journal of Pediatric Psychology. [IF=1.269, Cited=10, 7252711].
- Herr JC, Fowler JE, Howards SS, ..., Koons DJ (1985) Human antisperm monoclonal antibodies constructed postvasectomy.
Biology of Reproduction. [IF=0.959, Cited=17, 3922445].
- Herr JC, Summers TA, McGee RS, ..., Evans RJ (1986) Characterization of a monoclonal antibody to a conserved epitope on
human seminal vesicle-specific peptides: a novel probe/marker system for semen identification. Biology of Reproduction.
[IF=0.959, Cited=38, 2431723].
- Sigman M, Mundy P (1989) Social attachments in autistic children. Journal of the American Academy of Child and
Adolescent Psychiatry. [IF=3.59, Cited=58, 2464573].
- Cohen SE, Parmelee AH, Beckwith L, Sigman M (1986) Cognitive development in preterm infants: birth to 8 years. Journal
of Developmental and Behavioral Pediatrics. [IF=0.976, Cited=19, 3700656].
- Whaley SE, Sigman M, Espinosa MP, Neumann CG (1998) Infant predictors of cognitive development in an undernourished
Kenyan population. Journal of Developmental and Behavioral Pediatrics. [IF=0.976, Cited=9, 9648042].
- Lefkowitz ES, Sigman M, Au TK (2000) Helping mothers discuss sexuality and AIDS with adolescents. Child Development.
[IF=2.441, Cited=39, 11108102].
- Mehta A, Miner M, Sigman M (2013) Assessment of EndoPAT scores in men with vasculogenic and non-vasculogenic erectile
dysfunction. International Journal of Clinical Practice. [IF=0.665, Cited=8, 23241047].
- Bornstein MH, Sigman M (1986) Continuity in mental development from infancy. Child Development. [IF=2.441, Cited=135, 3956312].
- Weisz JR, Sigman M, Weiss B, Mosk J (1993) Parent reports of behavioral and emotional problems among children in Kenya,
Thailand, and the United States. Child Development. [IF=2.441, Cited=49, 8436040].
- Sigman M, Mundy P, Sherman T, Ungerer J (1986) Social interactions of autistic, mentally retarded and normal children
and their caregivers. Journal of Child Psychology and Psychiatry and Allied Disciplines. [IF=3.012, Cited=155, 3771681].
- Mundy P, Sigman M, Ungerer J, Sherman T (1986) Defining the social deficits of autism: the contribution of non-verbal
communication measures. Journal of Child Psychology and Psychiatry and Allied Disciplines. [IF=3.012, Cited=337, 3771682].
- McDonald MA, Mundy P, Kasari C, Sigman M (1989) Psychometric scatter in retarded, autistic preschoolers as measured by
the Cattell. Journal of Child Psychology and Psychiatry and Allied Disciplines. [IF=3.012, Cited=8, 2527864].
- Yirmiya N, Kasari C, Sigman M, Mundy P (1989) Facial expressions of affect in autistic, mentally retarded and normal
children. Journal of Child Psychology and Psychiatry and Allied Disciplines. [IF=3.012, Cited=106, 2793960].
- Capps L, Yirmiya N, Sigman M (1992) Understanding of simple and complex emotions in non-retarded children with autism.
Journal of Child Psychology and Psychiatry and Allied Disciplines. [IF=3.012, Cited=142, 1400699].
- Kasari C, Sigman M, Baumgartner P, Stipek DJ (1993) Pride and mastery in children with autism. Journal of Child
Psychology and Psychiatry and Allied Disciplines. [IF=3.012, Cited=26, 8463373].
- Capps L, Sigman M, Sena R, ..., Whalen C (1996) Fear, anxiety and perceived control in children of agoraphobic parents.
Journal of Child Psychology and Psychiatry and Allied Disciplines. [IF=3.012, Cited=35, 8735444].
- Dissanayake C, Sigman M, Kasari C (1996) Long-term stability of individual differences in the emotional responsiveness
of children with autism. Journal of Child Psychology and Psychiatry and Allied Disciplines. [IF=3.012, Cited=20, 8735446].
- Schwichtenberg AJ, Young GS, Sigman M, ..., Ozonoff S (2010) Can family affectedness inform infant sibling outcomes of
autism spectrum disorders? Journal of Child Psychology and Psychiatry and Allied Disciplines. [IF=3.012, Cited=39, 20546079].
- Ungerer JA, Sigman M, Beckwith L, ..., Parmelee AH (1983) Sleep behavior of preterm children at three years of age.
Developmental Medicine and Child Neurology. [IF=1.998, Cited=13, 6873491].
- Caplan R, Guthrie D, Mundy P, ..., Peacock WJ (1992) Non-verbal communication skills of surgically treated children with
infantile spasms. Developmental Medicine and Child Neurology. [IF=1.998, Cited=5, 1377138].
- Caplan R, Chugani HT, Messa C, ..., Mundy P (1993) Hemispherectomy for intractable seizures: presurgical cerebral
glucose metabolism and post-surgical non-verbal communication. Developmental Medicine and Child Neurology. [IF=1.998,
Cited=13, 9435774].
- Cvitanic OA, Cronan JJ, Sigman M, Landau ST (1993) Varicoceles: postoperative prevalence--a prospective study with color
Doppler US. Radiology. [IF=4.222, Cited=17, 8497618].
- Mark HF, Feldman D, Sigman M (1999) Conventional and molecular cytogenetic identification of a variant klinefelter
syndrome patient with a deleted X chromosome. Pathobiology. [IF=1.05, Cited=3, 9873230].
- Gligorich KM, Vaden RM, Shelton DN, ..., Welm BE (2013) Development of a screen to identify selective small molecules
active against patient-derived metastatic and chemoresistant breast cancer cells. Breast Cancer Research. [IF=1.764,
Cited=11, 23879992].
- Thurber CA, Sigman M, Weisz JR, Schmidt CK (1999) Homesickness in preadolescent and adolescent girls: risk factors,
behavioral correlates, and sequelae. None. [IF=None, Cited=8, 10353078].
- Johnson AD, Sigman M, Miller WJ (1970) Early actions of cadmium in the rat and domestic fowl testis. 3. Subcellular
location of injected 109 cadmium. None. [IF=None, Cited=12, 5481720].
- Johnson AD, Sigman M (1971) Early actions of cadmium in the rat and domestic fowl testis. IV. Autoradiographic location
of 115m cadmium. None. [IF=None, Cited=5, 5539091].
- Diuk CG, Slezak DF, Raskovsky I, ..., Cecchi GA (2012) A quantitative philology of introspection. Frontiers in
Integrative Neuroscience. [IF=0.96, Cited=3, 23015783].
- Fisch H, Sigman M, Jarow JP (1992) Are the bells and whistles for infertility practical in an office setting? None.
[IF=None, Cited=0, 10147978].
- Wilson JP, Raphael B, Meldrum L, ..., Sigman M (2000) Preventing PTSD in trauma survivors. Bulletin of the Menninger
Clinic. [IF=0.504, Cited=0, 10842447].
- Fox RA, Sigman M, Boekelheide K (2000) Transmembrane versus soluble stem cell factor expression in human testis. None.
[IF=None, Cited=0, 10901444].
- Caplan R, Guthrie D, Shields WD, ..., Vinters HV (1992) Early onset intractable seizures: nonverbal communication after
hemispherectomy. Journal of Developmental and Behavioral Pediatrics. [IF=0.976, Cited=0, 1401119].
- Neumann C, McDonald MA, Sigman M, Bwibo N (1992) Medical illness in school-age Kenyans in relation to nutrition,
cognition, and playground behaviors. Journal of Developmental and Behavioral Pediatrics. [IF=0.976, Cited=0, 1469106].
- Yirmiya N, Sigman M, Kasari C, Mundy P (1992) Empathy and cognition in high-functioning children with autism. Child
Development. [IF=2.441, Cited=0, 1551323].
- Flickinger CJ, Herr JC, McGee RS, ..., Conklin DJ (1990) Dynamics of a human seminal vesicle specific protein.
Andrologia. [IF=0.826, Cited=0, 1720288].
- Neumann C, McDonald MA, Sigman M, ..., Marquardt M (1991) Relationships between morbidity and development in mildly to
moderately malnourished Kenyan toddlers. Pediatrics. [IF=2.905, Cited=0, 1945634].
- Kasari C, Mundy P, Yirmiya N, Sigman M (1990) Affect and attention in children with Down syndrome. None. [IF=None,
Cited=0, 2143659].
- Becker EL, Sigman M, Oliver JM (1979) Superoxide production induced in rabbit polymorphonuclear leukocytes by synthetic
chemotactic peptides and A23187. American Journal of Pathology. [IF=1.235, Cited=0, 219701].
- McDonald MA, Sigman M, Ungerer JA (1989) Intelligence and behavior problems in 5-year-olds in relation to
representational abilities in the second year of life. Journal of Developmental and Behavioral Pediatrics. [IF=0.976,
Cited=0, 2708542].
- Sigman M (1989) Parallel process at case conferences. Bulletin of the Menninger Clinic. [IF=0.504, Cited=0, 2752227].
- Mundy P, Sigman M, Kasari C, Yirmiya N (1988) Nonverbal communication skills in Down syndrome children. Child
Development. [IF=2.441, Cited=0, 2963734].
- Sigman M, Vance ML (1987) Medical treatment of idiopathic infertility. Urologic Clinics of North America. [IF=1.04,
Cited=0, 3113025].
- Evans RJ, McGee RS, Sommers TA, ..., Herr JC (1987) Monoclonal antibody: new probe for sexual assault evidence. None.
[IF=None, Cited=0, 3617897].
- O'Connor MJ, Brill NJ, Sigman M (1986) Alcohol use in primiparous women older than 30 years of age: relation to infant
development. Pediatrics. [IF=2.905, Cited=0, 3748678].
- Sigman M, John R, Levinson E, Betts D (1985) Multiple family therapy with severely disturbed psychiatric patients. None.
[IF=None, Cited=0, 3911242].
- Sigman M, Parmelee AH (1974) Visual preferences of four-month-old premature and full-term infants. Child Development.
[IF=2.441, Cited=0, 4143886].
- Sigman M, Kopp CB, Parmelee AH, Jeffrey WE (1973) Visual attention and neurological organization in neonates. Child
Development. [IF=2.441, Cited=0, 4730531].
- Kopp CB, Sigman M, Parmelee AH (1973) Ordinality and sensory-motor series. Child Development. [IF=2.441, Cited=0, 4751302].
- Burzynski NJ, Sigman M, Martin TH (1971) Lipoma of the oral cavity: literature review and case report. None. [IF=None,
Cited=0, 4927662].
- Sigman M (1966) A cytochemical investigation of calcium in the rat enamel organ. None. [IF=None, Cited=0, 5223620].
- Ungerer JA, Sigman M (1984) The relation of play and sensorimotor behavior to language in the second year. Child
Development. [IF=2.441, Cited=0, 6207995].
- Ungerer JA, Sigman M (1983) Developmental lags in preterm infants from one to three years of age. Child Development.
[IF=2.441, Cited=0, 6354629].
- Cohen SE, Sigman M, Parmelee AH, Beckwith L (1982) Perinatal risk and developmental outcome in preterm infants. Seminars
in Perinatology. [IF=1.411, Cited=0, 7156991].
- Mark HF, Sheu M, Lopes L, ..., Sigman M (1995) Towards the development of a fluorescent in situ hybridization based
genotoxicologic assay for aneuploidy detection in sperm. None. [IF=None, Cited=0, 7497737].
- Becker EL, Koza EP, Sigman M (1978) Organophosphorus inhibition of lysosomal enzyme secretion from polymorphonuclear
leucocytes. Evidence of a lack of a requirement for esterase activation. Immunology. [IF=1.193, Cited=0, 750374].
- Jarow JP, Sigman M, Buch JP, Oates RD (1995) Delayed appearance of sperm after end-to-side vasoepididymostomy. Journal
of Urology. [IF=2.411, Cited=0, 7869486].
- Ruskin EM, Kasari C, Mundy P, Sigman M (1994) Attention to people and toys during social and object mastery in children
with Down syndrome. None. [IF=None, Cited=0, 7946251].
- McDonald MA, Sigman M, Espinosa MP, Neumann CG (1994) Impact of a temporary food shortage on children and their mothers.
Child Development. [IF=2.441, Cited=0, 8013230].
- Ruskin EM, Mundy P, Kasari C, Sigman M (1994) Object mastery motivation of children with Down syndrome. None. [IF=None,
Cited=0, 8148126].
- Kasari C, Freeman S, Mundy P, Sigman M (1995) Attention regulation by children with Down syndrome: coordinated joint
attention and social referencing looks. None. [IF=None, Cited=0, 8527109].
- Harris S, Kasari C, Sigman M (1996) Joint attention and language gains in children with Down syndrome. None. [IF=None,
Cited=0, 8735574].
- Lefkowitz ES, Kahlbaugh P, Au TK, Sigman M (1998) A longitudinal study of AIDS conversations between mothers and
adolescents. AIDS Education and Prevention. [IF=0.755, Cited=0, 9721387].
- Thurber CA, Sigman M (1998) Preliminary models of risk and protective factors for childhood homesickness: review and
empirical synthesis. Child Development. [IF=2.441, Cited=0, 9768478].
- Corona R, Dissanayake C, Arbelle S, ..., Sigman M (1998) Is affect aversive to young children with autism? Behavioral
and cardiac responses to experimenter distress. Child Development. [IF=2.441, Cited=0, 9914635].