Holm, Richard H

Publication with MATCHING institution:

Osterloh F, Sanakis Y, Staples RJ, ..., Holm RH (1999) A Molybdenum-Iron-Sulfur Cluster Containing Structural Elements
Relevant to the P-Cluster of Nitrogenase. Angewandte Chemie - International Edition. [IF=2.456, Cited=1, 34182709].
Xu G, Zhou J, Wang Z, ..., Chen XD (2019) Controlled Incorporation of Nitrides into W-Fe-S Clusters. Angewandte Chemie -
International Edition. [IF=2.456, Cited=5, 31489739].
Holm RH, Lo W (2016) Structural Conversions of Synthetic and Protein-Bound Iron-Sulfur Clusters. Chemical Reviews.
[IF=11.712, Cited=34, 27933770].
Groysman S, Holm RH (2009) Biomimetic chemistry of iron, nickel, molybdenum, and tungsten in sulfur-ligated protein
sites. Biochemistry. [IF=0.753, Cited=30, 19206188].
Venkateswara Rao P, Holm RH (2004) Synthetic analogues of the active sites of iron-sulfur proteins. Chemical Reviews.
[IF=11.712, Cited=202, 14871134].
Lee SC, Holm RH (2004) The clusters of nitrogenase: synthetic methodology in the construction of weak-field clusters.
Chemical Reviews. [IF=11.712, Cited=99, 14871151].
Holm RH, Solomon EI (2004) Preface: biomimetic inorganic chemistry. Chemical Reviews. [IF=11.712, Cited=53, 14871127].
Lee SC, Lo W, Holm RH (2014) Developments in the biomimetic chemistry of cubane-type and higher nuclearity iron-sulfur
clusters. Chemical Reviews. [IF=11.712, Cited=66, 24410527].
Holm RH, Kennepohl P, Solomon EI, Holm RH (1996) Structural and Functional Aspects of Metal Sites in Biology. Chemical
Reviews. [IF=11.712, Cited=696, 11848828].
Miao M, Willer MW, Holm RH (2000) Oxo/sulfidotungstate(VI) as precursors to W(VI)O2, W(VI)OS, and W(VI)S2 complexes and
W(IV)-dithiolene chelate rings. Inorganic Chemistry. [IF=0.986, Cited=4, 11232822].
Musgrave KB, Lim BS, Sung KM, ..., Hodgson K (2000) X-ray spectroscopy of enzyme active site analogues and related
molecules: bis(dithiolene)molybdenum(IV) and -tungsten(IV,VI) complexes with variant terminal ligands. Inorganic
Chemistry. [IF=0.986, Cited=2, 11154582].
Osterloh F, Achim C, Holm RH (2001) Molybdenum-iron-sulfur clusters of nuclearities eight and sixteen, including a
topological analogue of the P-cluster of nitrogenase. Inorganic Chemistry. [IF=0.986, Cited=8, 11170527].
Fomitchev DV, Lim BS, Holm RH (2001) Electron distribution in the nonclassical bis(dithiolene) electron transfer series
[M(CO)2(S2C2Me2)2]0/1-/2- (M = Mo, W): assessment by structural, spectroscopic, and density functional theory results.
Inorganic Chemistry. [IF=0.986, Cited=14, 11225106].
Daley CJ, Holm RH (2001) Reactivity of [Fe4S4(SR)4]2-,3- clusters with sulfonium cations: analogue reaction systems for
the initial step in biotin synthase catalysis. Inorganic Chemistry. [IF=0.986, Cited=12, 11375696].
Lim BS, Fomitchev DV, Holm RH (2001) Nickel dithiolenes revisited: structures and electron distribution from density
functional theory for the three-member electron-transfer series [Ni(S2C2Me2)2]0,1-,2-. Inorganic Chemistry. [IF=0.986,
Cited=32, 11487330].
Sung KM, Holm RH (2001) Substitution and oxidation reactions of bis(dithiolene)tungsten complexes of potential relevance
to enzyme sites. Inorganic Chemistry. [IF=0.986, Cited=7, 11511194].
Achim C, Bominaar EL, Staples RJ, ..., Holm RH (2001) Influence of extrinsic factors on electron transfer in a mixed-
valence Fe(2+)/Fe(3+) complex: experimental results and theoretical considerations. Inorganic Chemistry. [IF=0.986,
Cited=2, 11487347].
Hauser C, Bill E, Holm RH (2002) Single- and double-cubane clusters in the multiple oxidation states
[VFe(3)S(4)](3+,2+,1+). Inorganic Chemistry. [IF=0.986, Cited=17, 11896732].
Fomitchev DV, McLauchlan CC, Holm RH (2002) Heterometal cubane-type MFe(3)S(4) clusters (M = Mo, V) trigonally
symmetrized with hydrotris(pyrazolyl)borate(1-) and tris(pyrazolyl)methanesulfonate(1-) capping ligands. Inorganic
Chemistry. [IF=0.986, Cited=29, 11849099].
Zhou HC, Su W, Achim C, ..., Holm RH (2002) High-nuclearity sulfide-rich molybdenum[bond]iron[bond]sulfur clusters:
reevaluation and extension. Inorganic Chemistry. [IF=0.986, Cited=5, 12054998].
Gray TG, Holm RH (2002) Site-differentiated hexanuclear rhenium(III) cyanide clusters
[Re(6)Se(8)(PEt(3))(n)()(CN)(6)(-)(n)()](n)()(-)(4) (n = 4, 5) and kinetics of solvate ligand exchange on the cubic
[Re(6)Se(8)](2+) Core. Inorganic Chemistry. [IF=0.986, Cited=7, 12160409].
Sanakis Y, Yoo SJ, Osterloh F, ..., Münck E (2002) Determination of antiferromagnetic exchange coupling in the
tetrahedral thiolate-bridged diferrous complex [Fe2(SEt)6]2-. Inorganic Chemistry. [IF=0.986, Cited=2, 12495348].
Zhou HC, Holm RH (2003) Synthesis and reactions of cubane-type iron-sulfur-phosphine clusters, including soluble
clusters of nuclearities 8 and 16. Inorganic Chemistry. [IF=0.986, Cited=17, 12513073].
Jalilehvand F, Lim BS, Holm RH, ..., Hodgson KO (2003) X-ray absorption spectroscopy of a structural analogue of the
oxidized active sites in the sulfite oxidase enzyme family and related molybdenum(V) complexes. Inorganic Chemistry.
[IF=0.986, Cited=3, 12950200].
Zuo JL, Zhou HC, Holm RH (2003) Vanadium-iron-sulfur clusters containing the cubane-type [VFe3S4] core unit: synthesis
of a cluster with the topology of the PN cluster of nitrogenase. Inorganic Chemistry. [IF=0.986, Cited=17, 12870953].
Partyka DV, Staples RJ, Holm RH (2003) Nucleophilic reactivity and oxo/sulfido substitution reactions of MVIO3 Groups (M
= Mo, W). Inorganic Chemistry. [IF=0.986, Cited=10, 14632504].
Zhang Y, Holm RH (2004) Structural conversions of molybdenum-iron-sulfur edge-bridged double cubanes and P(n)-type
clusters topologically related to the nitrogenase P-cluster. Inorganic Chemistry. [IF=0.986, Cited=19, 14731029].
Jiang J, Holm RH (2004) An expanded set of functional groups in bis(dithiolene)tungsten(IV,VI) complexes related to the
active sites of tungstoenzymes, Including WIV-SR and WVI-O(SR). Inorganic Chemistry. [IF=0.986, Cited=6, 14966965].
Rao PV, Bhaduri S, Jiang J, Holm RH (2004) Sulfur bridging interactions of cis-planar NiII-S2N2 coordination units with
nickel(II), copper(I,II), zinc(II), and mercury(II): a library of bridging modes, including NiII(micro2-SR)2MI,II
rhombs. Inorganic Chemistry. [IF=0.986, Cited=22, 15360232].
Wang JJ, Kryatova OP, Rybak-Akimova EV, Holm RH (2004) Comparative kinetics and mechanism of oxygen and sulfur atom
transfer reactions mediated by bis(dithiolene) complexes of molybdenum and tungsten. Inorganic Chemistry. [IF=0.986,
Cited=13, 15578849].
Partyka DV, Holm RH (2004) Oxygen/sulfur substitution reactions of tetraoxometalates effected by electrophilic carbon
and silicon reagents. Inorganic Chemistry. [IF=0.986, Cited=8, 15606212].
Jiang J, Holm RH (2005) Reaction systems related to dissimilatory nitrate reductase: nitrate reduction mediated by
bis(dithiolene)tungsten complexes. Inorganic Chemistry. [IF=0.986, Cited=17, 15859288].
Berlinguette CP, Miyaji T, Zhang Y, Holm RH (2006) Precursors to clusters with the topology of the P(N) cluster of
nitrogenase: edge-bridged double cubane clusters [(Tp)2Mo2Fe6S8L4]z: synthesis, structures, and electron transfer
series. Inorganic Chemistry. [IF=0.986, Cited=13, 16499360].
Wang JJ, Tessier C, Holm RH (2006) Analogue reaction systems of selenate reductase. Inorganic Chemistry. [IF=0.986,
Cited=10, 16562954].
Pesavento RP, Berlinguette CP, Holm RH (2007) Stabilization of reduced molybdenum-iron-sulfur single- and double-cubane
clusters by cyanide ligation. Inorganic Chemistry. [IF=0.986, Cited=9, 17279830].
Sun J, Tessier C, Holm RH (2007) Sulfur ligand substitution at the nickel(II) sites of cubane-type and cubanoid NiFe3S4
clusters relevant to the C-clusters of carbon monoxide dehydrogenase. Inorganic Chemistry. [IF=0.986, Cited=25, 17346040].
Groysman S, Holm RH (2007) Synthesis and structures of bis(dithiolene)tungsten(IV,VI) thiolate and selenolate complexes:
approaches to the active sites of molybdenum and tungsten formate dehydrogenases. Inorganic Chemistry. [IF=0.986,
Cited=18, 17432849].
Deng L, Majumdar A, Lo W, Holm RH (2010) Stabilization of 3:1 site-differentiated cubane-type clusters in the
[Fe(4)S(4)](1+) core oxidation state by tertiary phosphine ligation: synthesis, core structural diversity, and S = 1/2
ground states. Inorganic Chemistry. [IF=0.986, Cited=9, 21038882].
Xi B, Holm RH (2011) The [MoFe3S4]2+ oxidation state: synthesis, substitution reactions, and structures of phosphine-
ligated cubane-type clusters with the S=2 ground state. Inorganic Chemistry. [IF=0.986, Cited=5, 21648449].
Huang D, Makhlynets OV, Tan LL, ..., Holm RH (2011) Fast carbon dioxide fixation by 2,6-pyridinedicarboxamidato-
nickel(II)-hydroxide complexes: influence of changes in reactive site environment on reaction rates. Inorganic
Chemistry. [IF=0.986, Cited=24, 21905646].
Lo W, Huang S, Zheng SL, Holm RH (2011) Cubane-type Fe4S4 clusters with chiral thiolate ligation: formation by ligand
substitution, detection of intermediates by 1H NMR, and solid state structures including spontaneous resolution upon
crystallization. Inorganic Chemistry. [IF=0.986, Cited=5, 21942299].
Majumdar A, Holm RH (2011) Specific incorporation of chalcogenide bridge atoms in molybdenum/tungsten-iron-sulfur single
cubane clusters. Inorganic Chemistry. [IF=0.986, Cited=8, 21985054].
Tenderholt AL, Hodgson K, Hodgson KO, ..., Solomon EI (2012) Substrate and metal control of barrier heights for oxo
transfer to Mo and W bis-dithiolene sites. Inorganic Chemistry. [IF=0.986, Cited=9, 22372518].
Lo W, Zhang P, Ling CC, ..., Holm RH (2012) Formation, spectroscopic characterization, and solution stability of an
[Fe4S4]2+ cluster derived from β-cyclodextrin dithiolate. Inorganic Chemistry. [IF=0.986, Cited=2, 22934734].
Zhang X, Huang D, Chen YS, Holm RH (2012) Synthesis of binucleating macrocycles and their nickel(II) hydroxo- and cyano-
bridged complexes with divalent ions: anatomical variation of ligand features. Inorganic Chemistry. [IF=0.986,
Cited=19, 23030366].
Hlavinka ML, Miyaji T, Staples RJ, Holm RH (2007) Hydroxide-promoted core conversions of molybdenum-iron-sulfur edge-
bridged double cubanes: oxygen-ligated topological PN clusters. Inorganic Chemistry. [IF=0.986, Cited=8, 17892284].
Wang JJ, Holm RH (2007) Silylation, sulfidation, and benzene-1,2-dithiolate complexation reactions of oxo- and
oxosulfidomolybdates(VI) and -tungstates(VI). Inorganic Chemistry. [IF=0.986, Cited=7, 18044955].
Scott TA, Holm RH (2008) VFe3S4 single and double cubane clusters: synthesis, structures, and dependence of redox
potentials and electron distribution on ligation and heterometal. Inorganic Chemistry. [IF=0.986, Cited=6, 18366157].
Pryadun R, Holm RH (2008) A new class of binuclear and trinuclear iron-sulfur clusters derived from
bis[bis(trimethylsilyl)amido]iron(II). Inorganic Chemistry. [IF=0.986, Cited=3, 18327895].
Tenderholt AL, Szilagyi RK, Holm RH, ..., Solomon EI (2008) Electronic control of the "Bailar twist" in formally d0-d2
molybdenum tris(dithiolene) complexes: a sulfur K-edge X-ray absorption spectroscopy and density functional theory
study. Inorganic Chemistry. [IF=0.986, Cited=17, 18517189].
Groysman S, Holm RH (2009) A series of mononuclear quasi-two-coordinate copper(I) complexes employing a sterically
demanding thiolate ligand. Inorganic Chemistry. [IF=0.986, Cited=17, 19138143].
Chakrabarti M, Deng L, Holm RH, ..., Bominaar EL (2009) Mössbauer, electron paramagnetic resonance, and theoretical
studies of a carbene-based all-ferrous Fe4S4 cluster: electronic origin and structural identification of the unique
spectroscopic site. Inorganic Chemistry. [IF=0.986, Cited=20, 19326927].
Huang D, Deng L, Sun J, Holm RH (2009) Cleavage of Ni-(mu(2)-S)-Ni bridges in dinuclear nickel(II) dithiolate pincer
complexes and related reactions. Inorganic Chemistry. [IF=0.986, Cited=8, 19459662].
Chakrabarti M, Deng L, Holm RH, ..., Bominaar EL (2010) The modular nature of all-ferrous edge-bridged double cubanes.
Inorganic Chemistry. [IF=0.986, Cited=5, 20073485].
Groysman S, Majumdar A, Zheng SL, Holm RH (2010) Reactions of monodithiolene tungsten(VI) sulfido complexes with
copper(I) in relation to the structure of the active site of carbon monoxide dehydrogenase. Inorganic Chemistry.
[IF=0.986, Cited=12, 20030373].
Nivorozhkin AL, Segal BM, Musgrave KB, ..., Holm RH (2000) Metallocyclopeptide complexes with MII(S.Cys)4 chromophores.
Inorganic Chemistry. [IF=0.986, Cited=8, 12526490].
Lim BS, Donahue JP, Holm RH (2000) Synthesis and structures of bis(dithiolene)molybdenum complexes related to the active
sites of the DMSO reductase enzyme family. Inorganic Chemistry. [IF=0.986, Cited=24, 11272534].
Osterloh F, Segal BM, Achim C, Holm RH (2000) Reduced mono-, di-, and tetracubane-type clusters containing the
[MoFe3S4]2+ core stabilized by tertiary phosphine ligation. Inorganic Chemistry. [IF=0.986, Cited=9, 12526378].
Sung KM, Holm RH (2000) Synthesis and structures of bis(dithiolene)-tungsten(IV) complexes related to the active sites
of tungstoenzymes. Inorganic Chemistry. [IF=0.986, Cited=4, 12526419].
Lim BS, Holm RH (2001) Bis(dithiolene)molybdenum analogues relevant to the DMSO reductase enzyme family: synthesis,
structures, and oxygen atom transfer reactions and kinetics. Journal of the American Chemical Society. [IF=2.573,
Cited=38, 11456813].
Sung KM, Holm RH (2001) Oxo transfer reactions mediated by bis(dithiolene)tungsten analogues of the active sites of
molybdoenzymes in the DMSO reductase family: comparative reactivity of tungsten and molybdenum. Journal of the American
Chemical Society. [IF=2.573, Cited=26, 11456814].
Lim BS, Willer MW, Miao M, Holm RH (2001) Monodithiolene molybdenum(V, VI) complexes: a structural analogue of the
oxidized active site of the sulfite oxidase enzyme family. Journal of the American Chemical Society. [IF=2.573,
Cited=25, 11516283].
Laplaza CE, Holm RH (2001) Helix-loop-helix peptides as scaffolds for the construction of bridged metal assemblies in
proteins: the spectroscopic A-cluster structure in carbon monoxide dehydrogenase. Journal of the American Chemical
Society. [IF=2.573, Cited=26, 11603975].
Musgrave KB, Laplaza CE, Holm RH, ..., Hodgson KO (2002) Structural characterization of metallopeptides designed as
scaffolds for the stabilization of nickel(II)-Fe(4)S(4) bridged assemblies by X-ray absorption spectroscopy. Journal of
the American Chemical Society. [IF=2.573, Cited=4, 11902899].
Sung KM, Holm RH (2002) Functional analogue reaction systems of the DMSO reductase isoenzyme family: probable mechanism
of S-oxide reduction in oxo transfer reactions mediated by bis(dithiolene)-tungsten(IV,VI) complexes. Journal of the
American Chemical Society. [IF=2.573, Cited=14, 11960460].
Zhang Y, Holm RH (2003) Synthesis of a molecular Mo2Fe6S9 cluster with the topology of the PN cluster of nitrogenase by
rearrangement of an edge-bridged Mo2Fe6S8 double cubane. Journal of the American Chemical Society. [IF=2.573, Cited=32, 12656626].
Zhang Y, Zuo JL, Zhou HC, Holm RH (2002) Rearrangement of symmetrical dicubane clusters into topological analogues of
the P cluster of nitrogenase: nature's choice? Journal of the American Chemical Society. [IF=2.573, Cited=24, 12452688].
Gray TG, Rudzinski CM, Meyer EE, ..., Nocera DG (2003) Spectroscopic and photophysical properties of hexanuclear
rhenium(III) chalcogenide clusters. Journal of the American Chemical Society. [IF=2.573, Cited=31, 12696894].
Szilagyi RK, Lim BS, Glaser T, ..., Solomon EI (2003) Description of the ground state wave functions of Ni dithiolenes
using sulfur K-edge X-ray absorption spectroscopy. Journal of the American Chemical Society. [IF=2.573, Cited=62, 15369373].
Panda R, Zhang Y, McLauchlan CC, ..., Holm RH (2004) Initial structure modification of tetrahedral to planar nickel(II)
in a nickel-iron-sulfur cluster related to the C-cluster of carbon monoxide dehydrogenase. Journal of the American
Chemical Society. [IF=2.573, Cited=14, 15149242].
Rao PV, Bhaduri S, Jiang J, ..., Holm RH (2005) On [Fe4S4]2+ -(mu2-SR)-M II bridge formation in the synthesis of an
A-cluster analogue of carbon monoxide dehydrogenase/acetylcoenzyme A synthase. Journal of the American Chemical Society.
[IF=2.573, Cited=20, 15701028].
Dey A, Glaser T, Moura JJG, ..., Solomon EI (2004) Ligand K-edge X-ray absorption spectroscopy and DFT calculations on
[Fe3S4]0,+ clusters: delocalization, redox, and effect of the protein environment. Journal of the American Chemical
Society. [IF=2.573, Cited=17, 15612726].
Dey A, Glaser T, Couture MMJ, ..., Solomon EI (2004) Ligand K-edge X-ray absorption spectroscopy of [Fe4S4]1+,2+,3+
clusters: changes in bonding and electronic relaxation upon redox. Journal of the American Chemical Society. [IF=2.573,
Cited=18, 15225075].
Bennett MV, Stoian S, Bominaar EL, ..., Holm RH (2005) Initial members of the family of molecular mid-valent high-
nuclearity iron nitrides: [Fe4N2X10]4- and [Fe10N8X12]5- (X = Cl-, Br-). Journal of the American Chemical Society.
[IF=2.573, Cited=14, 16131219].
Panda R, Berlinguette CP, Zhang Y, Holm RH (2005) Synthesis of MFe3S4 clusters containing a planar M(II) site (M = Ni,
Pd, Pt), a structural element in the C-cluster of carbon monoxide dehydrogenase. Journal of the American Chemical
Society. [IF=2.573, Cited=18, 16076217].
Berlinguette CP, Holm RH (2006) Edge-bridged Mo2Fe6S8 to pN-type Mo2Fe6S9 cluster conversion: structural fate of the
attacking sulfide/selenide nucleophile. Journal of the American Chemical Society. [IF=2.573, Cited=16, 16953641].
Wang JJ, Groysman S, Lee SC, Holm RH (2007) Synthesis of structural analogues of the oxidized sites in the xanthine
oxidoreductase enzyme family. Journal of the American Chemical Society. [IF=2.573, Cited=9, 17530853].
McNaughton RL, Lim BS, Knottenbelt SZ, ..., Kirk ML (2008) Spectroscopic and electronic structure studies of symmetrized
models for reduced members of the dimethylsulfoxide reductase enzyme family. Journal of the American Chemical Society.
[IF=2.573, Cited=12, 18341333].
Huang D, Holm RH (2010) Reactions of the terminal Ni(II)-OH group in substitution and electrophilic reactions with
carbon dioxide and other substrates: structural definition of binding modes in an intramolecular Ni(II)...Fe(II) bridged
site. Journal of the American Chemical Society. [IF=2.573, Cited=55, 20218565].
Zheng B, Chen XD, Zheng SL, Holm RH (2012) Selenium as a structural surrogate of sulfur: template-assisted assembly of
five types of tungsten-iron-sulfur/selenium clusters and the structural fate of chalcogenide reactants. Journal of the
American Chemical Society. [IF=2.573, Cited=15, 22424175].
Ha Y, Tenderholt AL, Holm RH, ..., Solomon EI (2014) Sulfur K-edge X-ray absorption spectroscopy and density functional
theory calculations on monooxo Mo(IV) and bisoxo Mo(VI) bis-dithiolenes: insights into the mechanism of oxo transfer in
sulfite oxidase and its relation to the mechanism of DMSO reductase. Journal of the American Chemical Society.
[IF=2.573, Cited=5, 24884723].
Deng L, Holm RH (2008) Stabilization of fully reduced iron-sulfur clusters by carbene ligation: the [FenSn]0 oxidation
levels (n = 4, 8). Journal of the American Chemical Society. [IF=2.573, Cited=41, 18593124].
Groysman S, Wang JJ, Tagore R, ..., Holm RH (2008) A biomimetic approach to oxidized sites in the xanthine
oxidoreductase family: synthesis and stereochemistry of tungsten(VI) analogue complexes. Journal of the American
Chemical Society. [IF=2.573, Cited=13, 18763763].
Deng L, Bill E, Wieghardt K, Holm RH (2009) Cubane-type Co4S4 clusters: synthesis, redox series, and magnetic ground
states. Journal of the American Chemical Society. [IF=2.573, Cited=5, 19722678].
Tenderholt AL, Wang JJ, Szilagyi RK, ..., Solomon EI (2010) Sulfur K-edge X-ray absorption spectroscopy and density
functional calculations on Mo(IV) and Mo(VI)=O bis-dithiolenes: insights into the mechanism of oxo transfer in DMSO
reductase and related functional analogues. Journal of the American Chemical Society. [IF=2.573, Cited=16, 20499905].
Troeppner O, Huang D, Holm RH, Ivanović-Burmazović I (2014) Thermodynamics and high-pressure kinetics of a fast carbon
dioxide fixation reaction by a (2,6-pyridinedicarboxamidato-hydroxo)nickel(II) complex. Dalton Transactions. [IF=0.808,
Cited=5, 24572679].
Scott TA, Berlinguette CP, Holm RH, Zhou HC (2005) Initial synthesis and structure of an all-ferrous analogue of the
fully reduced [Fe4S4]0 cluster of the nitrogenase iron protein. Proceedings of the National Academy of Sciences of the
United States of America. [IF=2.765, Cited=30, 15985547].
Lee SC, Holm RH (2003) Speculative synthetic chemistry and the nitrogenase problem. Proceedings of the National Academy
of Sciences of the United States of America. [IF=2.765, Cited=30, 12642670].
Huang D, Makhlynets OV, Tan LL, ..., Holm RH (2011) Kinetics and mechanistic analysis of an extremely rapid carbon
dioxide fixation reaction. Proceedings of the National Academy of Sciences of the United States of America. [IF=2.765,
Cited=39, 21220298].
Xu G, Wang Z, Ling R, ..., Holm RH (2018) Ligand metathesis as rational strategy for the synthesis of cubane-type
heteroleptic iron-sulfur clusters relevant to the FeMo cofactor. Proceedings of the National Academy of Sciences of the
United States of America. [IF=2.765, Cited=8, 29654147].
Beinert H, Holm RH, Münck E (1997) Iron-sulfur clusters: nature's modular, multipurpose structures. Science. [IF=7.729,
Cited=760, 9235882].

Publication with MISSING institution:

Bennett MV, Holm RH (2006) Self-assembly of a tetradecanuclear iron nitride cluster. Angewandte Chemie - International
Edition. [IF=2.456, Cited=9, 16858715].
Holm RH, Tang SC, Koch S, ..., Ibers JA (1976) Model system studies of axial ligation in the oxidized reaction states of
cytochrome P-450 enzymes. Advances in Experimental Medicine and Biology. [IF=0.945, Cited=0, 183472].
Laplaza CE, Holm RH (2002) Stability and nickel binding properties of peptides designed as scaffolds for the
stabilization of Ni(II)-Fe(4)S(4) bridged assemblies. Journal of Biological Inorganic Chemistry. [IF=0.755, Cited=4, 11941503].
Holm RH (1975) Iron-sulphur clusters in natural and synthetic systems. Endeavour. [IF=0.364, Cited=7, 54250].
Tenderholt AL, Szilagyi RK, Holm RH, ..., Solomon EI (2007) Sulfur K-edge XAS of WVO vs. MoVO bis(dithiolene) complexes:
contributions of relativistic effects to electronic structure and reactivity of tungsten enzymes. Journal of Inorganic
Biochemistry. [IF=0.935, Cited=12, 17720249].
Lo W, Scott TA, Zhang P, ..., Holm RH (2010) Stabilities of cubane type [Fe₄S₄(SR)₄](2-) clusters in partially aqueous
media. Journal of Inorganic Biochemistry. [IF=0.935, Cited=9, 21329647].
Tan LL, Holm RH, Lee SC (2013) Structural Analysis of Cubane-Type Iron Clusters. Polyhedron. [IF=0.635, Cited=12, 24072952].
Frankel RB, Herskovitz T, Averill BA, ..., Phillips WD (1974) Synthetic analogs of the active sites of iron-sulfur
proteins. 8. Some electronic properties of (Fe4S4(SR)4)3-, analogs of reduced bacterial ferredoxins. Biochemical and
Biophysical Research Communications. [IF=0.643, Cited=4, 4365892].
Tang SP, Spiro TG, Antanaitis C, ..., Mortensen LE (1975) Resonance Raman spectroscopic evidence for structural
variation among bacterial ferredoxin, HiPIP, and Fe4S4(SCH2Ph)42. Biochemical and Biophysical Research Communications.
[IF=0.643, Cited=7, 1111508].
Patterson GS, Holm RH (1975) Structural and electronic effects on the polarographic half-wave potentials of copper (II)
chelate complexes. None. [IF=None, Cited=17, 1125339].
Orme-Johnson WH, Holm RH (1978) Identification of iron--sulfur clusters in proteins. None. [IF=None, Cited=4, 213682].
McMillan RS, Renaud J, Reynolds JG, Holm RH (1979) Biologically related iron-sulfur clusters as reaction centers.
Reduction of acetylene to ethylene in systems based on [Fe4S4(SR)4]3-. Journal of Inorganic Biochemistry. [IF=0.935,
Cited=13, 512659].
Daley CJA, Holm RH (2003) Reactions of site-differentiated [Fe4S4]2+, 1+ clusters with sulfonium cations: reactivity
analogues of biotin synthase and other members of the S-adenosylmethionine enzyme family. Journal of Inorganic
Biochemistry. [IF=0.935, Cited=12, 14511891].
Enemark JH, Cooney JJA, Wang JJ, Holm RH (2004) Synthetic analogues and reaction systems relevant to the molybdenum and
tungsten oxotransferases. Chemical Reviews. [IF=11.712, Cited=115, 14871153].
Carney MJ, Papaefthymiou GC, Spartalian K, ..., Holm RH (1988) Ground spin state variability in [Fe4S4(SR)4]3-.
Synthetic analogs of the reduced clusters in ferredoxins and other iron-sulfur proteins: cases of extreme sensitivity of
electronic state and structure to extrinsic factors. Journal of the American Chemical Society. [IF=2.573, Cited=23, 22148785].
Caradonna JP, Harlan EW, Holm RH (1986) Thiol as an electron donor in molybdenum oxo-transferase analog reaction
systems: observations by fluorine-19 NMR spectroscopy and biological implications. Journal of the American Chemical
Society. [IF=2.573, Cited=5, 22283311].
Tang SC, Koch S, Papaefthymiou GC, ..., Holm RH (1976) Axial ligation modes in iron(III) Porphyrins. Models for the
oxidized reaction states of cytochrome P-450 enzymes and the molecular structure of iron(III) protoporphyrin IX dimethyl
ester p-nitrobenzenethiolate. Journal of the American Chemical Society. [IF=2.573, Cited=42, 177476].
Dawson JH, Holm RH, Trudell JR, ..., Tang SC (1976) Letter: Oxidized cytochrome P-450. Magnetic circular dichroism
evidence for thiolate ligation in the substrate-bound form. Implications for the catalytic mechanism. Journal of the
American Chemical Society. [IF=2.573, Cited=53, 1270706].
Lane RW, Ibers JA, Frankel RB, ..., Holm RH (1977) Synthetic analogues of the active sites of iron-sulfur proteins. 14.
Synthesis, properties, and structures of bis(o-xylyl-alpha,alpha'-dithiolato)ferrate(II, III) anions, analogues of
oxidized and reduced rubredoxin sites. Journal of the American Chemical Society. [IF=2.573, Cited=37, 830690].
Gillum WO, Mortenson LE, Chen JS, Holm RH (1977) Quantitative extrusions of the Fe4S4 cores of the active sites of
ferredoxins and the hydrogenase of Clostridium pasteurianum. Journal of the American Chemical Society. [IF=2.573,
Cited=40, 830694].
Lane RW, Gillum WO, Laskowski EJ, ..., Papaefthymiou GC (1977) Synthesis and electronic properties of the tetranuclear
trianions [Fe4S4(SR)4]3-, analogues of the 4-Fe active sites of reduced ferredoxins. Journal of the American Chemical
Society. [IF=2.573, Cited=5, 864137].
Hill CI, Renaud J, Holm RH, Mortenson IE (1977) Synthetic analogues of the active sites of iron-sulfur proteins. 15.
Comparative polarographic potentials of the [Fe4S4(SR)4]2 -- ,3 -- and clostridium pasteurianum ferredoxin redox
couples. Journal of the American Chemical Society. [IF=2.573, Cited=17, 850027].
Averill BA, Herskovitz T, Holm RH, Ibers JA (1973) Synthetic analogs of the active sites of iron-sulfur proteins. II.
Synthesis and structure of the tetra(mercapto-m 3 -sulfido-iron) clusters, (Fe 4 S 4 (SR) 4 ) 2- . Journal of the
American Chemical Society. [IF=2.573, Cited=51, 4708377].
Bobrik MA, Que L, Holm RH (1974) Synthetic analogs of the active sites of iron-sulfur proteins. IV. Ligand substitution
reactions of the tetranuclear clusters (Fe4S4(SR)4)2-. Journal of the American Chemical Society. [IF=2.573, Cited=2, 4810571].
Holm RH, Phillips WD, Averill BA, ..., Herskovitz T (1974) Synthetic analogs of the active sites of iron-sulfur
proteins. V. Proton resonance properties of the tetranuclear clusters (Fe4S4(SR)4). Evidence for dominant contact
interactions. Journal of the American Chemical Society. [IF=2.573, Cited=9, 4833642].
Holm RH, Holm RH, Averill BA, ..., Grunthaner FJ (1974) Equivalence of metal centers in the iron-sulfur protein active
site analogs (Fe4S4(SR)4)2-. Journal of the American Chemical Society. [IF=2.573, Cited=4, 4833717].
DePamphilis BV, Averill BA, Herskovitz T, ..., Holm RH (1974) Synthetic analogs of the active sites of iron-sulfur
proteins. VI. Spectral and redox characteristics of the tetranuclear clusters (Fe4S4(SR)4).2-. Journal of the American
Chemical Society. [IF=2.573, Cited=36, 4854591].
Que L, Bobrik MA, Ibers JA, Holm RH (1974) Synthetic analogs of the active sites of iron-sulfur proteins. VII. Ligand
substitution reactions of the tetranuclear clusters (Fe4S4(SR)4)2- and the structure of ((CH3)4N)2(Fe4S4(SC6H5)4).
Journal of the American Chemical Society. [IF=2.573, Cited=26, 4854592].
Que L, Anglin JR, Bobrik MA, ..., Holm RH (1974) Synthetic analogs of the active sites of iron-sulfur proteins. IX.
Formation and some electronic and reactivity properties of Fe4S4 Glycyl-L-cysteinylglycyl oligopeptide complexes
obtained by ligand substitution reactions. Journal of the American Chemical Society. [IF=2.573, Cited=15, 4416035].
Que L, Holm RH, Mortenson LE (1975) Letter: Extrusion of Fe2S2 and Fe4S4 cores from the active sites of ferredoxin
proteins. Journal of the American Chemical Society. [IF=2.573, Cited=18, 1133364].
Dukes GR, Holm RH (1975) Synthetic analogs of the active sites of iron-sulfur proteins; X. Kinetics and mechanism of the
ligand substitution reactions of arylthiols with the tetranuclear clusters [Fe4S4(SR)4]2 minus; Journal of the American
Chemical Society. [IF=2.573, Cited=12, 1133365].
Koch S, Tang SC, Holm RH, ..., Ibers JA (1975) Letter: Ferric porphyrin thiolates. Possible relationship to cytochrome
P-450 enzymes and the structure of (p-nitrobenzenethiolato)iron(III) protoporphyrin IX dimethyl ester. Journal of the
American Chemical Society. [IF=2.573, Cited=15, 1133375].
Yang CY, Johnson KH, Holm RH, Norman JG (1975) Letter: Theoretical model for the 4-Fe active sites in oxidized
ferredoxin and reduced "high-potential" proteins. Electronic structure of the analogue [Fe4S4(SCH3)4]2-. Journal of the
American Chemical Society. [IF=2.573, Cited=4, 1184875].
Lane RW, Ibers JA, Frankel RB, Holm RH (1975) Synthetic analogs of active sites of iron-sulfur proteins: bis
(o-xylyldithiolato) ferrate (III) monoanion, a structurally unconstrained model for the rubredoxin Fe-S4 unit.
Proceedings of the National Academy of Sciences of the United States of America. [IF=2.765, Cited=6, 1059080].
Hill CL, Steenkamp DJ, Holm RH, Singer TP (1977) Identification of the iron-sulfur center in trimethylamine
dehydrogenase. Proceedings of the National Academy of Sciences of the United States of America. [IF=2.765, Cited=19, 265519].
Kurtz DM, McMillan RS, Burgess BK, ..., Holm RH (1979) Identification of iron-sulfur centers in the iron-molybdenum
proteins of nitrogenase. Proceedings of the National Academy of Sciences of the United States of America. [IF=2.765,
Cited=16, 291915].
Coles CJ, Holm RH, Kurtz DM, ..., Wong GB (1979) Characterization of the iron-sulfur centers in succinate dehydrogenase.
Proceedings of the National Academy of Sciences of the United States of America. [IF=2.765, Cited=8, 226982].
Mascharak PK, Smith MC, Armstrong WH, ..., Holm RH (1982) Fluorine-19 chemical shifts as structural probes of metal-
sulfur clusters and the cofactor of nitrogenase. Proceedings of the National Academy of Sciences of the United States of
America. [IF=2.765, Cited=4, 6960364].
Donahue JP, Holm RH (1998) 3,4-Bis(1-adamantyl)-1,2-dithiete: the first structurally characterized dithiete unsupported
by a ring or benzenoid frame. None. [IF=None, Cited=2, 9760719].
McDonald CC, Phillips WD, Lovenberg W, Holm RH (1973) PMR studies on Clostridium pasteurianum ferredoxin: origins of
contact-shifted resonances and denaturation by dimethyl sulfoxide. Annals of the New York Academy of Sciences.
[IF=1.878, Cited=4, 4522445].
Ibers JA, Holm RH (1980) Modeling coordination sites in metallobiomolecules. Science. [IF=7.729, Cited=57, 7384796].
Conradson SD, Burgess BK, Vaughn SA, ..., Holm RH (1989) Cyanide and methylisocyanide binding to the isolated iron-
molybdenum cofactor of nitrogenase. Journal of Biological Chemistry. [IF=1.122, Cited=8, 2777773].
Conradson SD, Burgess BK, Holm RH (1988) Fluorine-19 chemical shifts as probes of the structure and reactivity of the
iron-molybdenum cofactor of nitrogenase. Journal of Biological Chemistry. [IF=1.122, Cited=6, 2843534].
Kurtz DM, Holm RH, Ruzicka FJ, ..., Singer TP (1979) The high potential iron-sulfur cluster of aconitase is a binuclear
iron-sulfur cluster. Journal of Biological Chemistry. [IF=1.122, Cited=11, 447628].
Paech C, Reynolds JG, Singer TP, Holm RH (1981) Structural identification of iron-sulfur clusters of the respiratory
chain-linked NADH dehydrogenase. Journal of Biological Chemistry. [IF=1.122, Cited=9, 7204398].

Holm, Richard H

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